| One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation | |
| Department | OSSO国家重点实验室 |
Li ZL(李泽龙)1,2; Liu JH(刘建华)1 ; Huang ZW(黄志威)1; Yang Y(杨英)1; Xia CG(夏春谷)1; Li FW(李福伟)1; Xia CG(夏春谷); Li FW(李福伟)
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| 2013 | |
| Source Publication | ACS Catalysis
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| ISSN | 2155-5435 |
| Volume | 3Issue:5Pages:839-845 |
| Abstract | In this work, we report a novel and facile procedure for a one-pot preparation of palladium nanoparticle catalysts supported on porous N-doped carbon (Pd@CNT) by direct carbonization of palladium-N-heterocyclic carbene coordination polymer (P-Pd-NHC). This method could be conveniently extended to the synthesis of the Ni and alloy (PdxNiy) nanoparticle catalysts (Ni@CN800, PdxNiy@CN800). The treatment temperature played an important role on the growth and properties of the resultant M@CNT, wherein M@CN800 carbonized at 800 ℃ showed well-monodispersed metal nanoparticles (MNPs), graphene-like layers of the N-doped carbon supports, and strong interaction between MNPs and the support. Pd@CN800 displayed high efficiency and stable recyclability toward the domino carbonylative synthesis of pyrazole derivatives. Interestingly, its catalytic performance has been even higher than that of the representative PdCl2(PPh3)2 within six runs. |
| Keyword | N-doped Carbon N-heterocyclic Carbenes Supported Catalysts Nanoparticles Carbonylation |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/cs400077r |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011) |
| Indexed By | SCI |
| If | 7.572 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4795 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Li ZL,Liu JH,Huang ZW,et al. One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation[J]. ACS Catalysis,2013,3(5):839-845. |
| APA | Li ZL.,Liu JH.,Huang ZW.,Yang Y.,Xia CG.,...&李福伟.(2013).One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation.ACS Catalysis,3(5),839-845. |
| MLA | Li ZL,et al."One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation".ACS Catalysis 3.5(2013):839-845. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ACS Catal.2013, 3, 8（406KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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