| Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols | |
| Department | OSSO国家重点实验室 |
Xie YJ(谢银君); Hu JH(胡建华); Jie P(解攀) ; Qian B(钱波); Huang HM(黄汉民); Huang HM(黄汉民)
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| 2013 | |
| Source Publication | Journal of the American Chemical Society
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| ISSN | 0002-7863 |
| Volume | 135Issue:49Pages:18327-18330 |
| Abstract | A new strategy was developed for intercepting the palladium alkyl species generated in Heck reaction via nucleophilic addition prior to the step of migratory insertion, which leads to a new palladium-catalyzed difunctionalization of enol ethers with aminals and alcohols to afford amino acetals. Mechanistic studies suggested that the cationic cyclometalated Pd(II) complex generated by the oxidative addition of aminal to a Pd(0) species was crucial for this unusual transformation. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ja410611b |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
| Indexed By | SCI |
| If | 11.444 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4781 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Xie YJ,Hu JH,Jie P,et al. Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols[J]. Journal of the American Chemical Society,2013,135(49):18327-18330. |
| APA | Xie YJ,Hu JH,Jie P,Qian B,Huang HM,&黄汉民.(2013).Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols.Journal of the American Chemical Society,135(49),18327-18330. |
| MLA | Xie YJ,et al."Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols".Journal of the American Chemical Society 135.49(2013):18327-18330. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| J. Am. Chem. Soc., 2（675KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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