Application of Sulfuryl Chloride for the Quick Construction of beta-Chlorotetrahydrofuran Derivatives from Homoallylic Alcohols under Mild Conditions | |
Department | OSSO国家重点实验室 |
Ceng XH(曾祥华)1,2; Miao CX(苗成霞)1; Wang SF(王寿峰)1; Xia CG(夏春谷)1; Sun W(孙伟)1; Sun W(孙伟) | |
2013 | |
Source Publication | Synthesis |
ISSN | 0039-7881 |
Volume | 45Issue:17Pages:2391-2396 |
Abstract | An efficient and mild method is reported for the construction of beta-chlorotetrahydrofuran derivatives by 5-endo chlorocycloetherification of homoallylic alcohols. The system employs sulfuryl chloride as the chlorinating agent under catalyst-free conditions. A variety of homoallylic alcohols with aryl or alkyl substituents were smoothly converted into beta-chlorotetrahydrofurans in yields up to 98%. |
Keyword | Homoallylic Alcohols Sulfuryl Chloride 5-endo Cyclization Tetrahydrofuran |
DOI | 10.1055/s-0033-1339351 |
Funding Organization | the National Natural Science Foundation of China (21073210;21133011;21103207) |
Indexed By | SCI |
If | 2.443 |
Language | 英语 |
Funding Project | 生物与仿生催化课题组;均相催化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4767 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Sun W(孙伟) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Ceng XH,Miao CX,Wang SF,et al. Application of Sulfuryl Chloride for the Quick Construction of beta-Chlorotetrahydrofuran Derivatives from Homoallylic Alcohols under Mild Conditions[J]. Synthesis,2013,45(17):2391-2396. |
APA | Ceng XH,Miao CX,Wang SF,Xia CG,Sun W,&孙伟.(2013).Application of Sulfuryl Chloride for the Quick Construction of beta-Chlorotetrahydrofuran Derivatives from Homoallylic Alcohols under Mild Conditions.Synthesis,45(17),2391-2396. |
MLA | Ceng XH,et al."Application of Sulfuryl Chloride for the Quick Construction of beta-Chlorotetrahydrofuran Derivatives from Homoallylic Alcohols under Mild Conditions".Synthesis 45.17(2013):2391-2396. |
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s-0033-1339351(1).pd(212KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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