| Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins | |
| Department | OSSO国家重点实验室 |
Wang XE(王晓娥)1,2; Miao CX(苗成霞)1 ; Wang SF(王寿峰)1; Xia CG(夏春谷)1; Sun W(孙伟)1; Sun W(孙伟)
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| 2013 | |
| Source Publication | ChemCatChem
 |
| ISSN | 1867-3880 |
| Volume | 5Issue:8Pages:2489-2494 |
| Abstract | The manganese and iron complexes with the tetradentate N ligand (1R,2R)-N,N'-dimethyl-N,N'-bis(1-methyl-2-benzimidazolylmethyl)cyclohexane-1,2-diamine have been synthesized and characterized. cis- configuration. Both the manganese and iron complexes are active catalysts for the asymmetric epoxidation of olefins with H2O2 as an oxidant and acetic acid as an additive. Up to 96% ee was observed for the epoxidation of α,β-unsaturated ketones at -20 ℃. |
| Keyword | Asymmetric Epoxidation Iron Manganese n(4)Ligand Olefin |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/cctc.201300102 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21073210) |
| Indexed By | SCI |
| If | 5.044 |
| Language | 英语 |
| Funding Project | 生物与仿生催化课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4765 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun W(孙伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Wang XE,Miao CX,Wang SF,et al. Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins[J]. ChemCatChem,2013,5(8):2489-2494. |
| APA | Wang XE,Miao CX,Wang SF,Xia CG,Sun W,&孙伟.(2013).Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins.ChemCatChem,5(8),2489-2494. |
| MLA | Wang XE,et al."Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins".ChemCatChem 5.8(2013):2489-2494. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2489_ftp(1).pdf（361KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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