| A facile protocol for the synthesis of mono-N-methyl anilines via formimidate intermediates | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Sun N(孙楠); Wang S(王帅) ; Mo WM(莫卫民); Hu BX(胡宝祥); Shen ZL(沈振陆); Hu XQ(胡信全)
| |
| 2010 | |
| Source Publication | Tetrahedron
 |
| ISSN | 0040-4020 |
| Volume | 66Pages:7142-7148 |
| Abstract | A general procedure for the preparation of mono-N-methyl anilines has been developed with excellent yields. This protocol relies on a NaBH3(OAc) reduction of formimidate intermediates that are quantitatively generated by treatment of primary substituted anilines with triethyl orthoformate under the catalysis of MCM-41-SO3H mesoporous zeolite. The newly developed procedure was facile, efficient, and environmentally benign. |
| Keyword | Mono-n-methyl Anilines Formimidate Mcm-41-so3h Mesoporous Zeolite Nabh3(Oac) Reduction |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Foundation of China (No. 20772111);the Natural Science Foundation of Zhejiang Province (Y407193) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/474 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Hu XQ(胡信全) |
| Recommended Citation GB/T 7714 | Sun N,Wang S,Mo WM,et al. A facile protocol for the synthesis of mono-N-methyl anilines via formimidate intermediates[J]. Tetrahedron,2010,66:7142-7148. |
| APA | 孙楠,王帅,莫卫民,胡宝祥,沈振陆,&胡信全.(2010).A facile protocol for the synthesis of mono-N-methyl anilines via formimidate intermediates.Tetrahedron,66,7142-7148. |
| MLA | 孙楠,et al."A facile protocol for the synthesis of mono-N-methyl anilines via formimidate intermediates".Tetrahedron 66(2010):7142-7148. |
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| 34_Tetrahedron,2010,（690KB） | 开放获取 | License | View Application Full Text | |||
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