| From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand | |
| Department | OSSO国家重点实验室 |
Wang JM(王佳敏)1,4 ; Li SG(李少光)1; Yang PJ(杨培菊)1; Huang XJ(黄晓卷)1; Yang XJ(杨晓娟)1; Wu B(吴彪)2,3; Wu B(吴彪)
| |
| The second department | erc国家工程研究中心 |
| 2013 | |
| Source Publication | CrystEngComm
 |
| ISSN | 1466-8033 |
| Volume | 15Issue:22Pages:4540-4548 |
| Abstract | A 1,5-naphthylene-bridged bis-bisurea receptor (L) has been designed and its coordination behavior with various anions has been examined in the solid state and in solution. This rigid "bis-bidentate" ligand can act as a linker to afford one-dimensional anion coordination polymers (ACPs) and dinuclear complexes with a wide range of anions. In the ACPs, the anions occupy the nodes and the polymeric structure is held solely by the coordination (hydrogen bonds) of the ligand to the anion. The sulfate ion forms three different complexes with L, two of which are discrete 1 : 2 (host-guest) anion complexes and the third is an ACP. The complexes of acetate and terephthalate are also 1D ACPs. On the other hand, benzoate, chloride and bromide ions form dinuclear complexes with L. Solution binding studies of L toward the anions were carried out by H-1 NMR, UV-vis and fluorescence titrations, from which the binding stoichiometry and stability constants were obtained. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c3ce26982e |
| Funding Organization | the National Natural Science Foundation of China (Grant No. 21271149) |
| Indexed By | SCI |
| If | 3.858 |
| Language | 英语 |
| Funding Project | 金属有机功能材料研究组;日常管理与大型仪器组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4721 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710069, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Wang JM,Li SG,Yang PJ,et al. From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand[J]. CrystEngComm,2013,15(22):4540-4548. |
| APA | Wang JM.,Li SG.,Yang PJ.,Huang XJ.,Yang XJ.,...&吴彪.(2013).From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand.CrystEngComm,15(22),4540-4548. |
| MLA | Wang JM,et al."From anion complexes to anion coordination polymers (ACPs): assembly with a 1,5-naphthylene bridged bis-bisurea ligand".CrystEngComm 15.22(2013):4540-4548. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| CrystEngComm, 2013, （1083KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment