| Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes | |
| Department | OSSO国家重点实验室 |
Zhao YX(赵艳霞)1,3; Lei YB(雷一波)2; Dong QS(董青松)1,3; Wu B(吴彪)2; Yang XJ(杨晓娟)1,2 ; Yang XJ(杨晓娟)
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| The second department | erc国家工程研究中心 |
| 2013 | |
| Source Publication | Chemistry - A European Journal
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| ISSN | 0947-6539 |
| Volume | 19Issue:36Pages:12059-12066 |
| Abstract | The reactions of dialumane [L(thf)Al-Al (thf)L] (1, L=[{(2,6- iPr2C6H3)NC(Me)}2]2_) with stilbene and styrene afforded the oxidation/insertion products [L(thf)Al(CH(Ph)-CH(Ph))AlL] (2) and [L(thf)Al(CH(Ph)-CH2)Al(thf)L] (3), respectively. In the presence of Na metal, precursor 1 reacted with butadienes, possibly through the reduced “dialumene” or the “carbene-like” :AlL species, to yield aluminacyclopentenes [LAl(CH2C(Me)=C(Me)CH2)Na]n (4a) and [Na(dme)3][LAl(CH2C(Me)=CHCH2)] (4b, dme=dimethoxyethane) as [1+4] cycloaddition products, as well as the [2+4] cycloaddition product 1,6-dialumina-3,8-cyclodecadiene, [{Na-(dme)}2][LAl(CH2C(Me)=C(Me)-CH2)2AlL] (5). The possible mechanisms of the cycloaddition reactions were studied by using DFT computations. |
| Keyword | Alkenes Aluminum Cycloaddition Insertion Reaction Mechanisms |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/chem.201300735 |
| Funding Organization | the National Natural Science Foundation of China (20972169;21273170) |
| Indexed By | SCI |
| If | 5.696 |
| Language | 英语 |
| Funding Project | 金属有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4719 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Yang XJ(杨晓娟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao YX,Lei YB,Dong QS,et al. Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes[J]. Chemistry - A European Journal,2013,19(36):12059-12066. |
| APA | Zhao YX,Lei YB,Dong QS,Wu B,Yang XJ,&杨晓娟.(2013).Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes.Chemistry - A European Journal,19(36),12059-12066. |
| MLA | Zhao YX,et al."Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes".Chemistry - A European Journal 19.36(2013):12059-12066. |
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| File Name/Size | DocType | Version | Access | License | ||
| Chem. Eur. J. 2013, （475KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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