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Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen
Department绿色化学研究发展中心
Cui XJ(崔新江)1; Dai XC(代兴超)1,2; Zhang Y(张妍)1; Deng YQ(邓友全)1; Shi F(石峰)1; Shi F(石峰)
The second departmentosso国家重点实验室
2014
Source PublicationChemical Science
ISSN2041-6520
Volume5Issue:2Pages:649-655
Abstract

CO2/H2 was successfully employed in alkylation reactions by performing CO2 reduction and amine N-methylation in one-pot. In the presence of a simple CuAlOx catalyst, N-methyl or N,N-dimethyl amines with different structures can be selectively synthesized with up to 96% yields by applying amine, nitrobenzene and nitrile as starting materials.

Subject Area物理化学与绿色催化
DOI10.1039/c3sc52676c
Funding Organizationthe National Natural Science Foundation of China (21073208;21203219;21173204);the Chinese Academy of Sciences
Indexed BySCI
If9.211
Language英语
Funding Project纳米催化课题组;绿色催化课题组
compositor第一作者单位
Citation statistics
Cited Times:158[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4705
Collection绿色化学研究发展中心
Corresponding AuthorShi F(石峰)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Cui XJ,Dai XC,Zhang Y,et al. Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen[J]. Chemical Science,2014,5(2):649-655.
APA Cui XJ,Dai XC,Zhang Y,Deng YQ,Shi F,&石峰.(2014).Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen.Chemical Science,5(2),649-655.
MLA Cui XJ,et al."Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen".Chemical Science 5.2(2014):649-655.
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