| Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia | |
| Department | 绿色化学研究发展中心 |
Cui XJ(崔新江)1,2 ; Dai XC(代兴超)1,2; Deng YQ(邓友全)1; Shi F(石峰)1; Shi F(石峰)
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| 2013 | |
| Source Publication | Chemistry A-Europeann Journal
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| ISSN | 0947-6539 |
| Volume | 19Issue:11Pages:3665-3675 |
| Abstract | The N-alkylation of amines or ammonia with alcohols is a valuable route for the synthesis of N-alkyl amines. However, as a potentially clean and economic choice for N-alkyl amine synthesis, non-noble metal catalysts with high activity and good selectivity are rarely reported. Normally, they are severely limited due to low activity and poor generality. Herein, a simple NiCu-FeOx catalyst was designed and prepared for the N-alkylation of ammonia or amines with alcohol or primary amines. N-alkyl amines with various structures were successfully synthesized in moderate to excellent yields in the absence of organic ligands and bases. Typically, primary amines could be efficiently transformed into secondary amines and N-heterocyclic compounds, and secondary amines could be N-alkylated to synthesize tertiary amines. Note that primary and secondary amines could be produced through a one-pot reaction of ammonia and alcohols. In addition to excellent catalytic performance, the catalyst itself possesses outstanding superiority, that is, it is air and moisture stable. Moreover, the magnetic property of this catalyst makes it easily separable from the reaction mixture and it could be recovered and reused for several runs without obvious deactivation. |
| Keyword | Alcohols Amination Ammonia Heterogeneous Catalysis Non-noble Metals |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/chem.201203417 |
| Funding Organization | the National Natural Science Foundation of China (21073208);the Chinese Academy of Sciences |
| Indexed By | SCI |
| If | 5.696 |
| Language | 英语 |
| Funding Project | 纳米催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4702 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Shi F(石峰) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Cui XJ,Dai XC,Deng YQ,et al. Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia[J]. Chemistry A-Europeann Journal,2013,19(11):3665-3675. |
| APA | Cui XJ,Dai XC,Deng YQ,Shi F,&石峰.(2013).Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia.Chemistry A-Europeann Journal,19(11),3665-3675. |
| MLA | Cui XJ,et al."Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia".Chemistry A-Europeann Journal 19.11(2013):3665-3675. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Ni-Cu ChemEurJ-publi（951KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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