LICP OpenIR  > 固体润滑国家重点实验室(LSL)
Noncovalent Microcontact Printing for Grafting Patterned Polymer Brushes on Graphene Films
Department固体润滑国家重点实验室
Gao TT(高婷婷)1,2; Wang XL(王晓龙)1; Yu B(于波)1; Wei QB(魏强兵)1,2; Xia YQ(夏延秋)1; Zhou F(周峰)1; Zhou F(周峰); Xia YQ(夏延秋)
2013
Source PublicationLangmuir
ISSN0743-7463
Volume29Issue:4Pages:1054-1060
AbstractThis article describes a simple and universal approach to prepare patterned polymer brushes on graphene-based substrate surfaces by microcontact printing (μCP) of initiator molecules and subsequent surface initiated atom transfer radical polymerization (SI-ATRP) method. Four different initiators are designed and have strong adhesion with graphenebased substrates through noncovalent interaction. Optical and fluorescence microscopy, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) were used to characterize the successful polymerization of vinyl monomers on substrate surfaces. To demonstrate the broad applicability of this strategy, polymer brushes with different functionalities including cationic and anionic polyelectrolyte, thermally and pH responsive polymers, as well as polymer patterns on different graphene-based surfaces are fabricated. Binary polymer brushes can also be easily prepared by further initiating the initiator backfilled in the bare areas.
Subject Area材料科学与物理化学
DOI10.1021/la304385r
Funding OrganizationNSFC (21125316);“Top Hundred Talents” Program of CAS
Indexed BySCI
If4.384
Language英语
Funding Project材料表面与界面行为研究组;空间润滑材料组
compositor第一作者单位
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4681
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorZhou F(周峰); Xia YQ(夏延秋)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Gao TT,Wang XL,Yu B,et al. Noncovalent Microcontact Printing for Grafting Patterned Polymer Brushes on Graphene Films[J]. Langmuir,2013,29(4):1054-1060.
APA Gao TT.,Wang XL.,Yu B.,Wei QB.,Xia YQ.,...&夏延秋.(2013).Noncovalent Microcontact Printing for Grafting Patterned Polymer Brushes on Graphene Films.Langmuir,29(4),1054-1060.
MLA Gao TT,et al."Noncovalent Microcontact Printing for Grafting Patterned Polymer Brushes on Graphene Films".Langmuir 29.4(2013):1054-1060.
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