| Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion | |
| Department | 固体润滑国家重点实验室 |
Li B(李斌)1 ; Yu B(于波)1; Huck, Wilhelm T. S.2; Liu WM(刘维民)1; Zhou F(周峰)1; Zhou F(周峰)
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| 2013 | |
| Source Publication | Journal of the American Chemical Society
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| ISSN | 0002-7863 |
| Volume | 135Issue:5Pages:1708-1710 |
| Abstract | Surface initiated atom transfer radical polymerization (SI-ATRP) was triggered after diffusion of a Cu-I/L activator generated at a working electrode. A stable [(CuL)-L-II]/[(CuL)-L-I] ratio gradient was formed at the gap between the working electrode and the initiator terminated substrate due to ion diffusion. The size of the gap can be used to dictate polymer growth kinetics at different gap distances. Gradient polymer brushes were grafted when substrate was placed at a tilting angle along [(CuL)-L-II]/[(CuL)-L-I] gradient. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1021/ja3116197 |
| Funding Organization | NSFC (21125316;51171202);973 project (2013CB632300);the Key Research Program of the Chinese Academy of Sciences (grant no. KJZD-EW-M01) |
| Indexed By | SCI |
| If | 11.444 |
| Language | 英语 |
| Funding Project | 材料表面与界面行为研究组;空间润滑材料组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4676 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Zhou F(周峰) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands |
| Recommended Citation GB/T 7714 | Li B,Yu B,Huck, Wilhelm T. S.,et al. Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion[J]. Journal of the American Chemical Society,2013,135(5):1708-1710. |
| APA | Li B,Yu B,Huck, Wilhelm T. S.,Liu WM,Zhou F,&周峰.(2013).Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion.Journal of the American Chemical Society,135(5),1708-1710. |
| MLA | Li B,et al."Electrochemically Mediated Atom Transfer Radical Polymerization on Nonconducting Substrates: Controlled Brush Growth through Catalyst Diffusion".Journal of the American Chemical Society 135.5(2013):1708-1710. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ja3116197-2.pdf（1371KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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