| In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes | |
| Department | 固体润滑国家重点实验室 |
Song ZH(宋增红)1,2; Cai MR(蔡美荣)1 ; Liang YM(梁永民)1; Fan MJ(凡明锦)1; Zhou F(周峰)1; Liu WM(刘维民)1; Fan MJ(凡明锦); Liu WM(刘维民)
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| 2013 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 3Issue:44Pages:21715-21721 |
| Abstract | Methoxy tris-ethoxy methylene benzotriazole (BTAG3) was synthesized and has good solubility in multiply-alkylated cyclopentanes (MACs) only when equal molar ratios of lithium salts, LiBF4, LiPF6, LiSO3CF3 or LiTFSI, were co-added into MACs due to the formation of ionic liquids (ILs), [Li(BTAG3)]BF4, [Li(BTAG3)]-PF6, [Li(BTAG3)]SO3CF3 and [Li(BTAG3)]TFSI. The as-synthesized ILs have better solubilities in MACs than the conventional imidazolium ILs, 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (L-F108) and 1-butyl-3-methylimidazolium tetrafluoroborate (L-B104) or the unfunctionalized lithium-based IL, [Li(G3)]TFSI, which are insoluble in MACs. They were evaluated as anti-wear and anti-corrosion additive of MACs for steel-steel contact at room temperature (RT). It was found that the ILs possessed excellent friction-reducing and anti-wear properties in MACs compared with zinc dialkyldithiophosphate. Besides, the presence of benzotriazole means that these synthetic ILs have good anti-corrosion properties compared with the conventional IL, L-B104. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1039/c3ra42092b |
| Funding Organization | the “973” Program (2013CB632300);NSFC (51105353;51175492) |
| Indexed By | SCI |
| If | 3.708 |
| Language | 英语 |
| Funding Project | 材料表面与界面行为研究组;空间润滑材料组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4672 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Fan MJ(凡明锦); Liu WM(刘维民) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Song ZH,Cai MR,Liang YM,et al. In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes[J]. RSC Advances,2013,3(44):21715-21721. |
| APA | Song ZH.,Cai MR.,Liang YM.,Fan MJ.,Zhou F.,...&刘维民.(2013).In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes.RSC Advances,3(44),21715-21721. |
| MLA | Song ZH,et al."In situ preparation of anti-corrosion ionic liquids as the lubricant additives in multiply-alkylated cyclopentanes".RSC Advances 3.44(2013):21715-21721. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 宋增红RSC.pdf（845KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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