| Synthesis of the Cu2ZnSn(S,Se)(4) alloys with tunable phase structure and composition via a novel non-toxic solution method | |
| Department | 清洁能源化学与材料实验室 |
Zhao Y(赵雲)1 ; Han XX(韩修训)1; Li W(李文)1,2; Liu L(刘亮)2,3; Tanaka, Tooru4; Han XX(韩修训)
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| The second department | 固体润滑国家重点实验室 |
| 2013 | |
| Source Publication | RSC advances
 |
| ISSN | 2046-2069 |
| Volume | 3Issue:48Pages:26160-26165 |
| Abstract | A new facile solution-based method to fabricate Cu2ZnSn(S,Se)4 (CZTSSe) alloys is presented without involving toxic solvent and post-growth selenization. Influences from the source concentration in the precursor solution and the annealing conditions on the product composition and phase transition are thoroughly examined. Experimental results show that the Se content can be adjusted over a wide composition region, which leads to highly controllable band-gap tailoring of CZTSSe absorbers. Furthermore, a wurtzite-derived phase structure is found readily to form even under such moderate synthesis conditions, and shows dependences on the chemical composition and the annealing temperature. The findings provide more freedom in the modification of CZTSSe material properties based on this novel phase structure. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1039/c3ra45094e |
| Funding Organization | the “Top Hundred Talents Program” of Chinese Academy of Sciences (CAS);the CAS – Japan Society for the Promotion of Science (JSPS) Collaborative Research Programme (Grant no. GJHZ1317) |
| Indexed By | SCI |
| If | 3.708 |
| Language | 英语 |
| Funding Project | 光电材料与器件研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4661 |
| Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Han XX(韩修训) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 4.Saga Univ, Dept Elect & Elect Engn, Saga 8408502, Japan |
| Recommended Citation GB/T 7714 | Zhao Y,Han XX,Li W,et al. Synthesis of the Cu2ZnSn(S,Se)(4) alloys with tunable phase structure and composition via a novel non-toxic solution method[J]. RSC advances,2013,3(48):26160-26165. |
| APA | Zhao Y,Han XX,Li W,Liu L,Tanaka, Tooru,&韩修训.(2013).Synthesis of the Cu2ZnSn(S,Se)(4) alloys with tunable phase structure and composition via a novel non-toxic solution method.RSC advances,3(48),26160-26165. |
| MLA | Zhao Y,et al."Synthesis of the Cu2ZnSn(S,Se)(4) alloys with tunable phase structure and composition via a novel non-toxic solution method".RSC advances 3.48(2013):26160-26165. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Synthesis of the Cu2（776KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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