| Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Zhao QL(赵启龙); Yang XJ(杨晓娟) ; Jia CD(贾传东); Huang XJ(黄晓卷); Wu B(吴彪)
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| 2010 | |
| Source Publication | Z. Anorg. Allg. Chem.
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| ISSN | 0044-2313 |
| Volume | 636Pages:1998-2003 |
| Abstract | Three copper(II) complexes, [Cu2(OAc)4L2]·2CH3OH (1), [CuBr2L'2(CH3OH)]·CH3OH (2a), and [CuBr2L'2(DMSO)]·0.5CH3OH (2b) {L = N-(9-anthracenyl)-N'-(3-pyridyl)urea and L' = N-[10-(10-methoxy-anthronyl)]-N'-(3-pyridyl)urea} have been synthesized by the reaction of L with the corresponding copper(II) salts. Complex 1 shows a dinuclear structure with a conventional “paddlewheel” motif, inwhich four acetate units bridge the two CuII ions. In complexes 2a and 2b, the anthracenyl ligand L has been converted to an anthronyl derivative L', and the central metal ion exhibits a distorted square pyramidal arrangement, with two pyridyl nitrogen atoms and two bromide ions defining the basal plane and the apical position is occupied by a solvent molecule (CH3OH in 2a and DMSO in 2b). |
| Keyword | N-(9-anthracenyl)-n'-(3-pyridyl)Urea N-[10-(10-methoxy-anthronyl)]-n'-(3-pyridyl)Urea Copper Fluorescence Supramolecular Chemistry |
| Subject Area | 金属有机功能材料 |
| Funding Organization | the National Natural Science Foundation of China (Grant No. 20872149) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/458 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Yang XJ(杨晓娟); Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Zhao QL,Yang XJ,Jia CD,et al. Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties[J]. Z. Anorg. Allg. Chem.,2010,636:1998-2003. |
| APA | 赵启龙,杨晓娟,贾传东,黄晓卷,&吴彪.(2010).Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties.Z. Anorg. Allg. Chem.,636,1998-2003. |
| MLA | 赵启龙,et al."Copper(II) Complexes with N-(9-anthracenyl)-N'-(3-pyridyl) urea (L) and a Derivative of L: Synthesis, Structure, and Fluorescent Properties".Z. Anorg. Allg. Chem. 636(2010):1998-2003. |
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