| An Efficient Rh/O-2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen | |
| Department | OSSO国家重点实验室 |
Zhang GY(张国营) ; Yang L(杨磊); Wang YY(王艳预); Xie YJ(谢银君); Huang HM(黄汉民); Huang HM(黄汉民)
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| 2013 | |
| Source Publication | Journal of the American Chemical Society
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| ISSN | 0002-7863 |
| Volume | 135Issue:24Pages:8850-8853 |
| Abstract | A novel and efficient Rh/O2 catalytic system has been developed and shown to catalyze highly efficient oxidative C−H activation/annulation reactions, producing a broad range of isoquinolinium salts with high turnover numbers (up to 740). Mechanistic studies provided strong evidence of facile oxidation of Rh(I) to Rh(III) by molecular oxygen facilitated by acid. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ja404414q |
| Funding Organization | the Chinese Academy of Sciences and the National Natural Science Foundation of China (21222203;21172226;21133011) |
| Indexed By | SCI |
| If | 11.444 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4567 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang GY,Yang L,Wang YY,et al. An Efficient Rh/O-2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen[J]. Journal of the American Chemical Society,2013,135(24):8850-8853. |
| APA | Zhang GY,Yang L,Wang YY,Xie YJ,Huang HM,&黄汉民.(2013).An Efficient Rh/O-2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen.Journal of the American Chemical Society,135(24),8850-8853. |
| MLA | Zhang GY,et al."An Efficient Rh/O-2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen".Journal of the American Chemical Society 135.24(2013):8850-8853. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ja404414q.pdf（333KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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