Improving capacitance performance of attapulgite/polypyrrole composites by introducing rhodamine B | |
Department | 环境材料与生态化学研究发展中心 |
Wang YJ(王赟姣)1,2; Liu P(刘鹏)1,2; Yang C(杨超)1,2; Mu B(牟斌)3; Wang AQ(王爱勤)3; Liu P(刘鹏) | |
2013 | |
Source Publication | Electrochimica Acta |
ISSN | 0013-4686 |
Volume | 89Pages:422-428 |
Abstract | The rhodamine B-attapulgite/polypyrrole (RhB-ATP/PPy) composites have been prepared by the in situ chemical oxidative polymerization method based on the self-assembly of pyrrole on the surface of the rhodamine B modified ATP (RhB-ATP). The morphologies of the RhB-ATP/PPy composites prepared with different feeding ratio of pyrrole and the RhB-ATP were compared with transmission electron microscope (TEM) technique. The electrochemical behaviors of the RhB-ATP/PPy composites were investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge–discharge. The results indicated that RhB did effectively improve the electrochemical performance and cycling stability of the RhB-ATP/PPy composite electrode, although RhB showed no obvious effect on the morphology of the nanocomposites. It was attributed to the fact that RhB and ATP provided a more convenient pathway to the charge carrier and RhB made the combination of the ATP and PPy much stronger. The maximum discharge capacity of the composites electrode achieved 587 F g−1 and kept 76% of its original specific capacitance after 500 cycles. |
Keyword | Conducting Polymer Attapulgite Rhodamine b Supercapacitors Cycling Stability |
Subject Area | 功能复合材料 |
DOI | 10.1016/j.electacta.2012.11.065 |
Funding Organization | the Natural Science Foundation of Gansu Province (Grant No. 1107RJZA213);the Fundamental Research Funds for the Central Universities (No. lzujbky-2011-21) |
Indexed By | SCI |
If | 4.086 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4554 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Liu P(刘鹏) |
Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Wang YJ,Liu P,Yang C,et al. Improving capacitance performance of attapulgite/polypyrrole composites by introducing rhodamine B[J]. Electrochimica Acta,2013,89:422-428. |
APA | Wang YJ,Liu P,Yang C,Mu B,Wang AQ,&刘鹏.(2013).Improving capacitance performance of attapulgite/polypyrrole composites by introducing rhodamine B.Electrochimica Acta,89,422-428. |
MLA | Wang YJ,et al."Improving capacitance performance of attapulgite/polypyrrole composites by introducing rhodamine B".Electrochimica Acta 89(2013):422-428. |
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