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Effect of number of grindings of attapulgite on enhanced swelling properties of the superabsorbent nanocomposites
Department环境材料与生态化学研究发展中心
Liu Y(刘毅)1,2; Chen H(陈红)1,2; Zhang JP(张俊平)1,3; Wang AQ(王爱勤)1,3; Wang AQ(王爱勤)
2013
Source PublicationJournal of Composite Materials
ISSN0021-9983
Volume47Issue:8Pages:969-978
AbstractThe incorporation of clay has become a preferred method for superabsorbent composite preparation because of its great influence on the swelling properties. The mechanical chemistry shows that grinding treatment could change the physical and chemical properties of clay. Therefore, in this article, the grinding treated attapulgite were used for preparation of sodium carboxymethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent nanocomposites by the solution polymerization using ammonium persulfate as an initiator and N,N'-methylenebisacrylamide as a crosslinker. The effects of number of grindings on the specific surface area and other characteristics of attapulgite, and the swelling ability, swelling kinetics, saline and pH sensitivity of the superabsorbent nanocomposites were systematically investigated. The results indicated that the increase in number of grindings could decrease the length of single crystals and dissociate part of crystal aggregates of attapulgite, which affected the dispersion of attapulgite in the polymeric matrix, thus leading to change in swelling behaviors of the superabsorbent nanocomposites. The swelling tests showed that the superabsorbent nanocomposites with attapulgite grinded for 6 times were the best in the reswelling abilities, initial swelling rate, saline and pH sensitivity.
KeywordSuperabsorbent Nanocomposite Attapulgite Grinding Treatment Sodium Carboxymethyl Cellulose Swelling Behavior
Subject Area功能复合材料
DOI10.1177/0021998312443398
Funding Organizationthe Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);the Foundation of Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province (No. HPK200901)
Indexed BySCI
If1.257
Language英语
Funding Project功能复合材料组
compositor第一作者单位
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Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4532
Collection环境材料与生态化学研究发展中心
Corresponding AuthorWang AQ(王爱勤)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Attapulgite Appl Technol, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Lanzhou 730000, Peoples R China
3.Huaiyin Inst Technol, Key Lab Attapulgite Sci & Appl Technol Jiangsu Pr, Huaian 223003, Peoples R China
Recommended Citation
GB/T 7714
Liu Y,Chen H,Zhang JP,et al. Effect of number of grindings of attapulgite on enhanced swelling properties of the superabsorbent nanocomposites[J]. Journal of Composite Materials,2013,47(8):969-978.
APA Liu Y,Chen H,Zhang JP,Wang AQ,&王爱勤.(2013).Effect of number of grindings of attapulgite on enhanced swelling properties of the superabsorbent nanocomposites.Journal of Composite Materials,47(8),969-978.
MLA Liu Y,et al."Effect of number of grindings of attapulgite on enhanced swelling properties of the superabsorbent nanocomposites".Journal of Composite Materials 47.8(2013):969-978.
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