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Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite
Department环境材料与生态化学研究发展中心
Wang YZ(王益哲)1,2; Shi XN(施小宁)1,2; Wang WB(王文波)1,3; Wang AQ(王爱勤)1,3; Wang AQ(王爱勤)
2013
Source PublicationJournal of Applied Polymer Science
ISSN0021-8995
Volume129Issue:3Pages:1080-1088
AbstractThe dispersion of attapulgite (APT) as nanorod-like single crystals is crucial to fully develop its functionality of one-dimensional nanometer material as a filler of composite materials. In this study, APT was dispersed by the assistance of ethanol during the high-pressure homogenization process to form individual nanorod-like crystals. The dispersed APT was used to prepare new sodium alginate-g-poly(sodium acrylate-co-styrene)/attapulgite (NaAlg-g-P(NaA-co-St)/APT) superabsorbent nanocomposites. The effect of ethanol/water ratio on the dispersion of crystal bundles of APT was investigated by field emission scanning electron microscopy, and the results indicate that APT crystal bundles were effectively disaggregated in (CH3CH2OH) : (H2O) 5 : 5 solution after homogenized at 50 MPa. The better dispersion of APT in NaAlg-g-P(NaA-co-St) matrix has clearly improved the gel strength (from 1300 Pa to 1410 Pa, = 100 rad/s), swelling capacity (442521 g/g), swelling rate (3.33034.5736 g/g/s), and reswelling ability of the superabsorbent nanocomposite. Moreover, the nanocomposites showed fast swellingdeswelling responsive behavior in different saline solutions.
KeywordResins Swelling Clay Composites Nanostructured Polymers
Subject Area功能复合材料
DOI10.1002/app.38786
Funding Organizationthe Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);Jiangsu Provincial Joint Innovation and Research Funding of Enterprises, Colleges and Institutes—Prospective Cooperative Research Project (No. BY2011194)
Indexed BySCI
If1.640
Language英语
Funding Project功能复合材料组
compositor第一作者单位
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4528
Collection环境材料与生态化学研究发展中心
Corresponding AuthorWang AQ(王爱勤)
Affiliation1.Chinese Acad Sci, Ctr Ecomat & Green Chem, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Chinese Acad Sci, R&D Ctr Xuyi Attapulgite Appl Technol, Lanzhou Inst Chem Phys, Xuyi 211700, Peoples R China
Recommended Citation
GB/T 7714
Wang YZ,Shi XN,Wang WB,et al. Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite[J]. Journal of Applied Polymer Science,2013,129(3):1080-1088.
APA Wang YZ,Shi XN,Wang WB,Wang AQ,&王爱勤.(2013).Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite.Journal of Applied Polymer Science,129(3),1080-1088.
MLA Wang YZ,et al."Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite".Journal of Applied Polymer Science 129.3(2013):1080-1088.
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