Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite | |
Department | 环境材料与生态化学研究发展中心 |
Wang YZ(王益哲)1,2; Shi XN(施小宁)1,2; Wang WB(王文波)1,3; Wang AQ(王爱勤)1,3; Wang AQ(王爱勤) | |
2013 | |
Source Publication | Journal of Applied Polymer Science |
ISSN | 0021-8995 |
Volume | 129Issue:3Pages:1080-1088 |
Abstract | The dispersion of attapulgite (APT) as nanorod-like single crystals is crucial to fully develop its functionality of one-dimensional nanometer material as a filler of composite materials. In this study, APT was dispersed by the assistance of ethanol during the high-pressure homogenization process to form individual nanorod-like crystals. The dispersed APT was used to prepare new sodium alginate-g-poly(sodium acrylate-co-styrene)/attapulgite (NaAlg-g-P(NaA-co-St)/APT) superabsorbent nanocomposites. The effect of ethanol/water ratio on the dispersion of crystal bundles of APT was investigated by field emission scanning electron microscopy, and the results indicate that APT crystal bundles were effectively disaggregated in (CH3CH2OH) : (H2O) 5 : 5 solution after homogenized at 50 MPa. The better dispersion of APT in NaAlg-g-P(NaA-co-St) matrix has clearly improved the gel strength (from 1300 Pa to 1410 Pa, = 100 rad/s), swelling capacity (442521 g/g), swelling rate (3.33034.5736 g/g/s), and reswelling ability of the superabsorbent nanocomposite. Moreover, the nanocomposites showed fast swellingdeswelling responsive behavior in different saline solutions. |
Keyword | Resins Swelling Clay Composites Nanostructured Polymers |
Subject Area | 功能复合材料 |
DOI | 10.1002/app.38786 |
Funding Organization | the Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);Jiangsu Provincial Joint Innovation and Research Funding of Enterprises, Colleges and Institutes—Prospective Cooperative Research Project (No. BY2011194) |
Indexed By | SCI |
If | 1.640 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4528 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Wang AQ(王爱勤) |
Affiliation | 1.Chinese Acad Sci, Ctr Ecomat & Green Chem, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, R&D Ctr Xuyi Attapulgite Appl Technol, Lanzhou Inst Chem Phys, Xuyi 211700, Peoples R China |
Recommended Citation GB/T 7714 | Wang YZ,Shi XN,Wang WB,et al. Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite[J]. Journal of Applied Polymer Science,2013,129(3):1080-1088. |
APA | Wang YZ,Shi XN,Wang WB,Wang AQ,&王爱勤.(2013).Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite.Journal of Applied Polymer Science,129(3),1080-1088. |
MLA | Wang YZ,et al."Ethanol-assisted dispersion of attapulgite and its effect on improving properties of alginate-based superabsorbent nanocomposite".Journal of Applied Polymer Science 129.3(2013):1080-1088. |
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