| Charge-assisted Hydrogen-bonded Linear Second-sphere Assemblies [MII(DABP)3]3[Cr(C2O4)3]2.14H2O (M5Cu, Ni, Fe, Zn, and Mn) with a Discrete (H2O)14 Cluster of S6 Symmetry | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
诸葛福瑜; Wu B(吴彪); Dong LH(董立欢); Yang J(杨进); Christoph Janiak; Tang N(唐宁); Yang XJ(杨晓娟)
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| 2010 | |
| Source Publication | Aust. J. Chem.
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| ISSN | 0004-9425 |
| Volume | 63Pages:1358-1364 |
| Abstract | A series of isomorphous second-sphere coordination compounds [MII(DABP)3]3[Cr(C2O4)3]2 14H2O (DABP¼ 5,50-diamino-2,20-bipyridine; M¼Cu (1), Ni (2), Fe (3), Zn (4), and Mn (5)) have been constructed through multiple charge-assisted N–H--O hydrogen-bonding interactions between the oxalate ligands in [Cr(C2O4)3]3-(unit B) and the NH2 groups in the [M(DABP)3]2þ complex (unit A). The chiral [M(DABP)3]2þ cations and [Cr(C2O4)3]3 anions with the same L (or D) configuration interdigitate alternately, affording linear A3B2 secondary building units. Two adjacent A3B2 units adopting opposite configurations are linked by a six-cornered star-shaped 14-water cluster of S6 symmetry (unit C) to form a racemic 1D linear chain –A3B2(L)–C–A3B2(D)–C–. The microstructure of compound 1 shows a 3D flower-like morphology. |
| Subject Area | 金属有机功能材料 |
| Funding Organization | the National Natural Science Foundation of China (grant no. 20872149);the “Bairen Jihua” project of the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/450 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | 诸葛福瑜,Wu B,Dong LH,et al. Charge-assisted Hydrogen-bonded Linear Second-sphere Assemblies [MII(DABP)3]3[Cr(C2O4)3]2.14H2O (M5Cu, Ni, Fe, Zn, and Mn) with a Discrete (H2O)14 Cluster of S6 Symmetry[J]. Aust. J. Chem.,2010,63:1358-1364. |
| APA | 诸葛福瑜.,吴彪.,董立欢.,杨进.,Christoph Janiak.,...&杨晓娟.(2010).Charge-assisted Hydrogen-bonded Linear Second-sphere Assemblies [MII(DABP)3]3[Cr(C2O4)3]2.14H2O (M5Cu, Ni, Fe, Zn, and Mn) with a Discrete (H2O)14 Cluster of S6 Symmetry.Aust. J. Chem.,63,1358-1364. |
| MLA | 诸葛福瑜,et al."Charge-assisted Hydrogen-bonded Linear Second-sphere Assemblies [MII(DABP)3]3[Cr(C2O4)3]2.14H2O (M5Cu, Ni, Fe, Zn, and Mn) with a Discrete (H2O)14 Cluster of S6 Symmetry".Aust. J. Chem. 63(2010):1358-1364. |
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