| Biomimetic Total Synthesis of (+)-Chabranol | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Wang XL(王晓磊); Zheng J(郑婕); Chen Q(陈强); Zheng HJ(郑怀基); He YP(贺永平); Yang J(杨娟) ; She XG(厍学功)
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| 2010 | |
| Source Publication | J. Org. Chem.
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| ISSN | 1520-6904 |
| Volume | 75Pages:5392-5394 |
| Abstract | A concise, biomimetic total synthesis of the unprecedented terpenoid skeleton (þ)-chabraol has been accomplished via 6 steps from the chiral epoxide 7, involving an intramolecular Prins double cyclization to yield the bicyclo[2.2.1] core of the natural product as the key step. The absolute configuration of natural chabranol was also designated through the first asymmetric total synthesis. |
| Subject Area | 物理化学 |
| Funding Organization | the generous financial support by the MOST (2010CB833200);the NSFC (20872054;20732002) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/442 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | She XG(厍学功) |
| Recommended Citation GB/T 7714 | Wang XL,Zheng J,Chen Q,et al. Biomimetic Total Synthesis of (+)-Chabranol[J]. J. Org. Chem.,2010,75:5392-5394. |
| APA | 王晓磊.,郑婕.,陈强.,郑怀基.,贺永平.,...&厍学功.(2010).Biomimetic Total Synthesis of (+)-Chabranol.J. Org. Chem.,75,5392-5394. |
| MLA | 王晓磊,et al."Biomimetic Total Synthesis of (+)-Chabranol".J. Org. Chem. 75(2010):5392-5394. |
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