Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability
Department先进润滑与防护材料研究发展中心
Wang X(王雪)1,2; Wang TM(王廷梅)3; Yang C(杨超)4; Li HD(李海东)1,2; Liu P(刘鹏)1,2; Liu P(刘鹏)
The second department固体润滑国家重点实验室
2013
Source PublicationApplied Surface Science
ISSN0169-4332
Volume287Pages:242-251
AbstractWell-defined flake-like polypyrrole grafted graphene nanosheets composites (PPy-g-GNS) were fab-ricated by the in-situ chemical oxidative grafting polymerization of pyrrole in the presence of the4-aminophenyl modified graphene nanosheets (AP-GNS), which were prepared via the coupling reactionof the graphene nanosheets (GNS) with diazonium salt. The flake-like PPy-g-GNS composite showed thehigh conductivity at room temperature. A maximum discharge capacitance of 191.2 F/g at the scan rate of 10 mV/s could be achieved in the three-electrode cell electrochemical testing in 1.0 mol/L NaNO3 electrolyte solution. It is higher than those of the AP-GNS, pure PPy, and the GNS/PPy composite prepared with the unmodified graphene nanosheets (GNS). The flake-like PPy-g-GNS composites also exhibitedthe excellent electrochemical stability even after 1000 cycles. It revealed the synergistic effect betweenthe conducting polymer and the carbon-based support.
KeywordPolypyrrole Graphene Composites Grafting Polymerization Electrochemical Property
DOI10.1016/j.apsusc.2013.09.134
Funding Organizationthe Natural Science Foundationof Gansu Province (Grant no. 1107RJZA213);the Fundamental Research Funds for the Central Universities (no. lzujbky-2011-21);the National Science Foundation for Fostering Talents in Basic Research of the National Natural Science Foundation of China(Grant no. J1103307)
Indexed BySCI
If2.538
Language英语
Funding Project聚合物自润滑复合材料组
compositor第三作者单位
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4376
Collection中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorLiu P(刘鹏)
Affiliation1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
4.Guilin Univ Technol, Coll Mat Sci & Engn, Guilin 541004, Peoples R China
Recommended Citation
GB/T 7714
Wang X,Wang TM,Yang C,et al. Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability[J]. Applied Surface Science,2013,287:242-251.
APA Wang X,Wang TM,Yang C,Li HD,Liu P,&刘鹏.(2013).Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability.Applied Surface Science,287,242-251.
MLA Wang X,et al."Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability".Applied Surface Science 287(2013):242-251.
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