Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability | |
Department | 先进润滑与防护材料研究发展中心 |
Wang X(王雪)1,2; Wang TM(王廷梅)3; Yang C(杨超)4; Li HD(李海东)1,2; Liu P(刘鹏)1,2; Liu P(刘鹏) | |
The second department | 固体润滑国家重点实验室 |
2013 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 287Pages:242-251 |
Abstract | Well-defined flake-like polypyrrole grafted graphene nanosheets composites (PPy-g-GNS) were fab-ricated by the in-situ chemical oxidative grafting polymerization of pyrrole in the presence of the4-aminophenyl modified graphene nanosheets (AP-GNS), which were prepared via the coupling reactionof the graphene nanosheets (GNS) with diazonium salt. The flake-like PPy-g-GNS composite showed thehigh conductivity at room temperature. A maximum discharge capacitance of 191.2 F/g at the scan rate of 10 mV/s could be achieved in the three-electrode cell electrochemical testing in 1.0 mol/L NaNO3 electrolyte solution. It is higher than those of the AP-GNS, pure PPy, and the GNS/PPy composite prepared with the unmodified graphene nanosheets (GNS). The flake-like PPy-g-GNS composites also exhibitedthe excellent electrochemical stability even after 1000 cycles. It revealed the synergistic effect betweenthe conducting polymer and the carbon-based support. |
Keyword | Polypyrrole Graphene Composites Grafting Polymerization Electrochemical Property |
DOI | 10.1016/j.apsusc.2013.09.134 |
Funding Organization | the Natural Science Foundationof Gansu Province (Grant no. 1107RJZA213);the Fundamental Research Funds for the Central Universities (no. lzujbky-2011-21);the National Science Foundation for Fostering Talents in Basic Research of the National Natural Science Foundation of China(Grant no. J1103307) |
Indexed By | SCI |
If | 2.538 |
Language | 英语 |
Funding Project | 聚合物自润滑复合材料组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4376 |
Collection | 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liu P(刘鹏) |
Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 4.Guilin Univ Technol, Coll Mat Sci & Engn, Guilin 541004, Peoples R China |
Recommended Citation GB/T 7714 | Wang X,Wang TM,Yang C,et al. Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability[J]. Applied Surface Science,2013,287:242-251. |
APA | Wang X,Wang TM,Yang C,Li HD,Liu P,&刘鹏.(2013).Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability.Applied Surface Science,287,242-251. |
MLA | Wang X,et al."Well-defined flake-like polypyrrole grafted graphene nanosheets composites as electrode materials for supercapacitors with enhanced cycling stability".Applied Surface Science 287(2013):242-251. |
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