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Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity
Department固体润滑国家重点实验室
Wang JJ(王军军)1,2; Pu JB(蒲吉斌)1; Zhang GA(张广安)1; Wang LP(王立平)1; Wang LP(王立平)
2013
Source PublicationACS Applied Materials & Interfaces
ISSN1944-8244
Volume5Issue:11Pages:5015-5024
AbstractSuperthick diamond-like carbon (DLC) films [(Six-DLC/Siy-DLC)n/DLC] were deposited on 304 stainless steel substrates by using a plane hollow cathode plasma enhanced chemical vapor deposition method. The structure was investigated by scanning electron microscopy and transmission electron microscopy. Chemical bonding was examined by Raman, Auger electron, and X-ray photoelectron spectroscopy techniques. Mechanical and tribological properties were evaluated using nanoindentation, scratch, interferometry, and reciprocating-sliding friction testing. The results showed that implantation of a silicon ion into the substrate and the architecture of the tensile stress/compressive stress structure decreased the residual stress to almost 0, resulting in deposition of (Six-DLC/Siy-DLC)n/DLC films with a thickness of more than 50 μm. The hardness of the film ranged from 9 to 23 GPa, and the adhesion strength ranged from 4.6 to 57 N depending on the thickness of the film. Friction coefficients were determined in three tested environments, namely, air, water, and oil. Friction coefficients were typically below 0.24 and as low as 0.02 in a water environment. The as-prepared superthick films also showed an ultrahigh load-bearing capacity, and no failure was detected in the reciprocating wear test with contact pressure higher than 3.2 GPa. Reasons for the ultrahigh load-bearing capacity are proposed in combination with the finite-element method.
KeywordSuperthick Dlc Film Load-bearing Capacity Finite-element Method
Subject Area材料科学与物理化学
DOI10.1021/am400778p
Funding Organizationthe National Natural Science Foundation of China (Grant 11172300)
Indexed BySCI
If5.900
Language英语
Funding Project低维材料摩擦学课题组
compositor第一作者单位
Citation statistics
Cited Times:88[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4358
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang LP(王立平)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Wang JJ,Pu JB,Zhang GA,et al. Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity[J]. ACS Applied Materials & Interfaces,2013,5(11):5015-5024.
APA Wang JJ,Pu JB,Zhang GA,Wang LP,&王立平.(2013).Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity.ACS Applied Materials & Interfaces,5(11),5015-5024.
MLA Wang JJ,et al."Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity".ACS Applied Materials & Interfaces 5.11(2013):5015-5024.
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