Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity | |
Department | 固体润滑国家重点实验室 |
Wang JJ(王军军)1,2; Pu JB(蒲吉斌)1; Zhang GA(张广安)1; Wang LP(王立平)1; Wang LP(王立平) | |
2013 | |
Source Publication | ACS Applied Materials & Interfaces |
ISSN | 1944-8244 |
Volume | 5Issue:11Pages:5015-5024 |
Abstract | Superthick diamond-like carbon (DLC) films [(Six-DLC/Siy-DLC)n/DLC] were deposited on 304 stainless steel substrates by using a plane hollow cathode plasma enhanced chemical vapor deposition method. The structure was investigated by scanning electron microscopy and transmission electron microscopy. Chemical bonding was examined by Raman, Auger electron, and X-ray photoelectron spectroscopy techniques. Mechanical and tribological properties were evaluated using nanoindentation, scratch, interferometry, and reciprocating-sliding friction testing. The results showed that implantation of a silicon ion into the substrate and the architecture of the tensile stress/compressive stress structure decreased the residual stress to almost 0, resulting in deposition of (Six-DLC/Siy-DLC)n/DLC films with a thickness of more than 50 μm. The hardness of the film ranged from 9 to 23 GPa, and the adhesion strength ranged from 4.6 to 57 N depending on the thickness of the film. Friction coefficients were determined in three tested environments, namely, air, water, and oil. Friction coefficients were typically below 0.24 and as low as 0.02 in a water environment. The as-prepared superthick films also showed an ultrahigh load-bearing capacity, and no failure was detected in the reciprocating wear test with contact pressure higher than 3.2 GPa. Reasons for the ultrahigh load-bearing capacity are proposed in combination with the finite-element method. |
Keyword | Superthick Dlc Film Load-bearing Capacity Finite-element Method |
Subject Area | 材料科学与物理化学 |
DOI | 10.1021/am400778p |
Funding Organization | the National Natural Science Foundation of China (Grant 11172300) |
Indexed By | SCI |
If | 5.900 |
Language | 英语 |
Funding Project | 低维材料摩擦学课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4358 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang LP(王立平) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Wang JJ,Pu JB,Zhang GA,et al. Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity[J]. ACS Applied Materials & Interfaces,2013,5(11):5015-5024. |
APA | Wang JJ,Pu JB,Zhang GA,Wang LP,&王立平.(2013).Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity.ACS Applied Materials & Interfaces,5(11),5015-5024. |
MLA | Wang JJ,et al."Interface Architecture for Superthick Carbon-Based Films toward Low Internal Stress and Ultrahigh Load-Bearing Capacity".ACS Applied Materials & Interfaces 5.11(2013):5015-5024. |
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王军军-ACS.pdf(1837KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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