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Microstructure, phase transition and tribological performances of Ni3Si-based self-lubricating composite coatings
Department固体润滑国家重点实验室
Niu MY(牛牧野)1,2; Bi QL(毕秦岭)1; Zhu SY(朱圣宇)1; Yang J(杨军)1; Liu WM(刘维民)1; Bi QL(毕秦岭)
2013
Source PublicationJournal of Alloys and Compounds
ISSN0925-8388
Volume555Pages:367-374
AbstractNi3Si-based composite coatings with various contents of MoS2 and BaF2/CaF2 were prepared by hot-pressed sintering. The effects of MoS2 and BaF2/CaF2 on mechanical and tribology properties of the coatings were evaluated in the temperature range of 25–800 ℃, respectively. The results showed that MoS2 decomposes to Mo2S3 during the fabricating process, and Ni31Si12 phase was formed when the hot-pressing temperature rising up to 1050 ℃. The coatings had high friction coefficients below 200 ℃ because of the decomposition of MoS2. It is interesting to note that the Ni31Si12 phase in all of the coatings is fully transformed to Ni3Si at 800 ℃ during the friction process. The coating containing 15 wt.% MoS2 and 10 wt.% BaF2/CaF2 exhibited the lowest friction coefficient when the temperature exceeded 400 ℃. A glaze layer was formed on the worn surface at higher temperature. XRD results showed that the worn surface of the coating contained BaMoO4, CaMoO4, and NiMoO4 at 800 ℃, and these oxides act as effective lubricants at this temperature. The synergistic action of the oxides is responsible for the reduction of the friction.
KeywordCoating Materials Intermetallics Powder Metallurgy Phase Transitions X-ray Diffraction
Subject Area材料科学与物理化学
DOI10.1016/j.jallcom.2012.12.079
Funding Organizationthe National Natural Science Foundation of China (51075383);the National 973 Project (2013CB632300)
Indexed BySCI
If2.726
Language英语
Funding Project高温抗磨材料组
compositor第一作者单位
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4275
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorBi QL(毕秦岭)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Niu MY,Bi QL,Zhu SY,et al. Microstructure, phase transition and tribological performances of Ni3Si-based self-lubricating composite coatings[J]. Journal of Alloys and Compounds,2013,555:367-374.
APA Niu MY,Bi QL,Zhu SY,Yang J,Liu WM,&毕秦岭.(2013).Microstructure, phase transition and tribological performances of Ni3Si-based self-lubricating composite coatings.Journal of Alloys and Compounds,555,367-374.
MLA Niu MY,et al."Microstructure, phase transition and tribological performances of Ni3Si-based self-lubricating composite coatings".Journal of Alloys and Compounds 555(2013):367-374.
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