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Photoluminescence degradation and color shift studies of annealed BaMgAl10O17:Eu2+ phosphor
Department固体润滑国家重点实验室
Zhang ZH(张占辉); Wang YH(王育华); Li XX(李小侠); Dou YK(都云昆); Liu WJ(刘文晶)
2007
Source PublicationJournal of Luminescence
ISSN0022-2313
Volume122-123Pages:1003-1005
AbstractThe photoluminescence (PL) in UV and VUV regions, such as excitation and emission spectra, PL intensity, full-width at halfmaximum (FWHM) and chromaticity coordinates, of pre- and post-annealed BaMgAl10O17:Eu2+ (BAM) samples were investigated. The observed more PL degradation under VUV excitation was assigned to the formation of defects (extinction centers or new Eu2+ centers) which decreased the luminance efficiency of Eu2+ in mirror plane. The increasing y value of chromaticity coordinates that appeared in annealed samples under 147nm excitation was attributed to the migration of Eu2+ from mirror plane to spinel block, which induced long wavelength emission. Therefore, besides the well-accepted oxidation mechanism, the migration of Eu2+ also led to the decrease of blue luminescent centers, and there by is responsible for the PL degradation, too. The conclusion of this work revealed a more full-scale and precise mechanism of thermal degradation than the conventional one.
KeywordBamgal10o17:Eu2++ Thermal Degradation Color Shift
Subject Area材料科学与物理化学
Funding OrganizationNSFC (50272026);the National High Technology Research and Development Program of China (2003AA324020);the Excellent Young Teachers Program of MOE, China (2002);the Natural Science Foundation of Gansu Province (ZS031-A25-033-C)
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4050
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWang YH(王育华)
Recommended Citation
GB/T 7714
Zhang ZH,Wang YH,Li XX,et al. Photoluminescence degradation and color shift studies of annealed BaMgAl10O17:Eu2+ phosphor[J]. Journal of Luminescence,2007,122-123:1003-1005.
APA 张占辉,王育华,李小侠,都云昆,&刘文晶.(2007).Photoluminescence degradation and color shift studies of annealed BaMgAl10O17:Eu2+ phosphor.Journal of Luminescence,122-123,1003-1005.
MLA 张占辉,et al."Photoluminescence degradation and color shift studies of annealed BaMgAl10O17:Eu2+ phosphor".Journal of Luminescence 122-123(2007):1003-1005.
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