Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds | |
Department | 固体润滑国家重点实验室 |
Xia XF(夏晓峰); Shu XZ(舒兴中); Ji KG(纪克攻); Yang YF(杨艳芳); Ali Shaukat; Liu XY(刘雪原); Liang YM(梁永民) | |
2010 | |
Source Publication | Journal of Organic Chemistry |
ISSN | 0022-3263 |
Volume | 75Pages:2893-2902 |
Abstract | A mild platinum-catalyzed oxidative dehydrogenation of R,β-C(sp3)-H bonds of tertiary amines in thepresence of ambient oxygen is revealed, and the in situ formed enamines subsequently reacting withvarious nitroolefins resulted in the development of two one-pot synthetic protocols involving Michaeladdition-elimination and Michael addition-cyclization. By using different functionalized nitroolefinscompatible with the current oxidative conditions, two types of structurally divergent products,trisubstituted enamines and chromano[2,3-b]piperidines, could be expediently accessed, respectively. |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Science Foundation (NSF-20732002, NSF-20090443, NSF-20872052) |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3950 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liang YM(梁永民) |
Recommended Citation GB/T 7714 | Xia XF,Shu XZ,Ji KG,et al. Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds[J]. Journal of Organic Chemistry,2010,75:2893-2902. |
APA | 夏晓峰.,舒兴中.,纪克攻.,杨艳芳.,Ali Shaukat.,...&梁永民.(2010).Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds.Journal of Organic Chemistry,75,2893-2902. |
MLA | 夏晓峰,et al."Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds".Journal of Organic Chemistry 75(2010):2893-2902. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
20102893-2902.pdf(1069KB) | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment