| Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst | |
| Department | OSSO国家重点实验室 |
Wu M(吴妹)1,2; Chou LJ(丑凌军)1 ; Song HL(宋焕玲)1; Song HL(宋焕玲)
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| 2012 | |
| Source Publication | Catalysis Letters
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| ISSN | 1011-372X |
| Volume | 142Issue:5Pages:627-636 |
| Abstract | Nickel modified Titanium silicalite 1 (TS-1) catalysts provided an environmentally benign and effective method for butadiene epoxidation. Certain loading of modified Ni in our system significantly promoted TS-1 catalytic activity. The product vinyloxirane (VO) was obtained with high yield of 0.49 mol/L (theoretic equilibrium value 0.52 mol/L). The turnover number (TON, determined as the molar VO obtained per molar Ti atom) reached 1,140. Besides, the catalyst kept high activity during five runs of reusability test. XRD, N2 adsorption and desorption, TPR, XPS, FT-IR and DR UV–Vis were employed to characterize the specific Ni role to Ti-site in Ni/TS-1 catalysts. |
| Keyword | Butadiene Epoxidation Vinyloxirane Titanium Silicalite 1 Nickel |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1007/s10562-012-0792-6 |
| Funding Organization | the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China |
| Indexed By | SCI |
| If | 2.244 |
| Language | 英语 |
| Funding Project | 多相催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3891 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Song HL(宋焕玲) |
| Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Wu M,Chou LJ,Song HL,et al. Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst[J]. Catalysis Letters,2012,142(5):627-636. |
| APA | Wu M,Chou LJ,Song HL,&宋焕玲.(2012).Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst.Catalysis Letters,142(5),627-636. |
| MLA | Wu M,et al."Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst".Catalysis Letters 142.5(2012):627-636. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B48.Catal Lett (2012（675KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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