| Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone | |
| Department | OSSO国家重点实验室 |
| Zhang WJ(张文娟)1,2; Liu SF(刘绍峰)1,2; Sun WH(孙文华)1,2,3; Hao X(郝项)1,2; Carl Redshaw4; Sun WH(孙文华) | |
| 2012 | |
| Source Publication | New Journal of Chemistry
 |
| ISSN | 1144-0546 |
| Volume | 36Issue:11Pages:2392-2396 |
| Abstract | A series of trimetallic yttrium complexes, L7Y3Cl2 [L = N-(2-methylquinolin-8-yl)-p-R-benzamides, 1: R = H; 2: R = OMe; 3: R = Me; 4: R = Cl], has been synthesized by the stoichiometric reaction of YCl3(THF)2 with the corresponding potassium amidates. All complexes have been characterized by elemental analysis and NMR spectroscopy. The molecular structure of complex 1 bearing seven amidate ligands was confirmed by single-crystal X-ray diffraction. Screening of these complexes, in the presence of BnOH, for ring-opening polymerization of caprolactone (e-CL) revealed effective activities. |
| Subject Area | 物理化学 |
| DOI | 10.1039/c2nj40711f |
| Funding Organization | National Natural Science Foundation of China (No. 20904059). CR wishes to thank the EPSRC for an overseas travel grant (EP/H031855/1) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3883 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Affiliation | 1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England |
| Recommended Citation GB/T 7714 | Zhang WJ,Liu SF,Sun WH,et al. Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone[J]. New Journal of Chemistry,2012,36(11):2392-2396. |
| APA | Zhang WJ,Liu SF,Sun WH,Hao X,Carl Redshaw,&孙文华.(2012).Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone.New Journal of Chemistry,36(11),2392-2396. |
| MLA | Zhang WJ,et al."Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone".New Journal of Chemistry 36.11(2012):2392-2396. |
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| File Name/Size | DocType | Version | Access | License | ||
| B40.New J. Chem., 20（876KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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