| A novel BaCl2-TiO2-SnO2 catalyst for the oxidative dehydrogenation of ethane | |
| Department | OSSO国家重点实验室 |
Wang ZL(王仲来)1,2 ; Chen L(陈龙)1; Zou GJ(邹国军)1; Luo X(雒旭)1,2; Gao RX(高润雄)1; Chou LJ(丑凌军)1; Wang XL(王晓来)1; Chou LJ(丑凌军); Wang XL(王晓来)
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| 2012 | |
| Source Publication | Catalysis Communications
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| ISSN | 1566-7367 |
| Volume | 25Pages:45-49 |
| Abstract | A novel BaCl2–TiO2–SnO2 catalyst was prepared and studied for the oxidative dehydrogenation of ethane (ODE). Slight changes in textual properties and crystal structures of the catalyst were observed after ODE reaction. Nonetheless, both Ba2+ and Cl− ions were found to segregate on catalyst surface during the reaction. The vital and positive effects of Cl− ions in the catalyst have been demonstrated by control experiments with catalyst free of Cl− ions. The BaCl2–TiO2–SnO2 catalyst show good activity and selectivity in ODE reaction, making it an alternative for ethylene synthesis using a low-cost feedstock such as ethane. |
| Keyword | Ethane Oxidative Dehydrogenation Bacl2-tio2-sno2 Catalyst Segregation Positive Effects Of Cl- Ions |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.catcom.2012.03.023 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 多相催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3869 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军); Wang XL(王晓来) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10039, Peoples R China |
| Recommended Citation GB/T 7714 | Wang ZL,Chen L,Zou GJ,et al. A novel BaCl2-TiO2-SnO2 catalyst for the oxidative dehydrogenation of ethane[J]. Catalysis Communications,2012,25:45-49. |
| APA | Wang ZL.,Chen L.,Zou GJ.,Luo X.,Gao RX.,...&王晓来.(2012).A novel BaCl2-TiO2-SnO2 catalyst for the oxidative dehydrogenation of ethane.Catalysis Communications,25,45-49. |
| MLA | Wang ZL,et al."A novel BaCl2-TiO2-SnO2 catalyst for the oxidative dehydrogenation of ethane".Catalysis Communications 25(2012):45-49. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B26.Catalysis Commun（591KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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