Effect of epimerization of d-glucose on photocatalytic hydrogen generation over Pt/TiO2 | |
Department | OSSO国家重点实验室 |
Zhou MH(周美华)1; Li YX(李越湘)1; Peng SQ(彭绍琴)1; Lu GX(吕功煊)2; Li SB(李树本)2; Li YX(李越湘) | |
The second department | erc国家工程研究中心 |
2012 | |
Source Publication | Catalysis Communications |
ISSN | 1566-7367 |
Volume | 18Pages:21-25 |
Abstract | Effects of α-d- and β-d-glucose as electron donors on photocatalytic hydrogen generation over Pt/TiO2 have been investigated. α-d-Glucose exhibits better photocatalytic activity for hydrogen evolution than β-d-glucose. The effects of initial pH of the anomer solutions on photocatalytic hydrogen generation have also been studied. Weak basic condition is favorable for the photocatalytic hydrogen generation. There is a large activity difference between α-d- and β-d-glucose under neutral condition, while the difference is very small under basic and acidic conditions. The possible mechanism was discussed. |
Keyword | Photocatalysis Hydrogen Generation Alpha-d-glucose Beta-d-glucose Alpha-beta Equilibrium |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.catcom.2011.11.017 |
Funding Organization | NSFC (20763006 and 21163012);973 project (2009CB220003);the Natural Science Foundation of the Jiangxi Province (2010JZH0096);Research Fund of Education Ministry of Jiangxi, China (GJJ09041) |
Indexed By | SCI |
If | 2.915 |
Language | 英语 |
Funding Project | 环境催化与清洁能源研究组;环境催化与氢能源研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3868 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 精细石油化工中间体国家工程研究中心(ERC) |
Corresponding Author | Li YX(李越湘) |
Affiliation | 1.Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Zhou MH,Li YX,Peng SQ,et al. Effect of epimerization of d-glucose on photocatalytic hydrogen generation over Pt/TiO2[J]. Catalysis Communications,2012,18:21-25. |
APA | Zhou MH,Li YX,Peng SQ,Lu GX,Li SB,&李越湘.(2012).Effect of epimerization of d-glucose on photocatalytic hydrogen generation over Pt/TiO2.Catalysis Communications,18,21-25. |
MLA | Zhou MH,et al."Effect of epimerization of d-glucose on photocatalytic hydrogen generation over Pt/TiO2".Catalysis Communications 18(2012):21-25. |
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B25.Catalysis Commun(524KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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