LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde
DepartmentOSSO国家重点实验室
Zhao YW(赵应伟); Lei M(雷敏); Yang L(杨磊); Han F(韩峰); Li Z(李臻); Xia CG(夏春谷); Xia CG(夏春谷)
2012
Source PublicationOrganic and Biomolecular Chemistry
ISSN1477-0520
Volume10Issue:45Pages:8956-8959
Abstract

The nucleophilic addition of thiocarbamate imidazolium ylide to aldehyde triggered sequential intramolecular N to O migration of thiocarbonyl amide group and reversible oxygen–sulfur rearrangement to afford 2-imidazolium alkylcarbamothioate. The ortho group on phenyl of aldehyde strongly affects the balance of the O- to S-rearrangement.

Subject Area物理化学与绿色催化
DOI10.1039/c2ob26520f
Funding Organizationthe National Natural Science Foundation of China (NSFC) (grant numbers 21133011;21173241)
Indexed BySCI
If3.568
Language英语
Funding Project均相催化研究组
compositor第一作者单位
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/3854
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorXia CG(夏春谷)
AffiliationChinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhao YW,Lei M,Yang L,et al. Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde[J]. Organic and Biomolecular Chemistry,2012,10(45):8956-8959.
APA Zhao YW.,Lei M.,Yang L.,Han F.,Li Z.,...&夏春谷.(2012).Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde.Organic and Biomolecular Chemistry,10(45),8956-8959.
MLA Zhao YW,et al."Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde".Organic and Biomolecular Chemistry 10.45(2012):8956-8959.
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