| Homometallic Silver(I) Complexes of a Heterotopic NHC-Bridged Bis-Bipyridine Ligand | |
| Department | OSSO国家重点实验室 |
Cui FJ(崔凤娟)1,3; Yang PJ(杨培菊)1 ; Huang XJ(黄晓卷)1; Yang XJ(杨晓娟)1; Wu B(吴彪)1,2; Wu B(吴彪)
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| The second department | erc国家工程研究中心 |
| 2012 | |
| Source Publication | Organometallics
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| ISSN | 0276-7333 |
| Volume | 31Issue:9Pages:3512-3518 |
| Abstract | By varying the metal to ligand ratio, stepwise formation of a series of homonuclear silver(I) complexes of a carbene-bridged bis-bipyridine ligand (L) was achieved. In the mononuclear 1:2 complex [AgL2]Br (1) only the carbene carbon is involved in the metal coordination, while both of the 2,2′-bipyridine (bpy) arms are free. When the amount of silver(I) ion was increased, isomorphous 2:2 dinuclear complexes with different counteranions, [Ag2L2]X2 (X = Br– (2a), PF6– (2b), BPh4– (2c)), were synthesized from the ligand LX, in which the carbene carbon and one of the bpy units participate in the coordination with silver(I) ions. Further addition of AgI salt afforded the one-dimensional coordination polymer {[Ag3L2](PF6)3·4CH3CN}n (3), wherein the hanging bipyridine units also coordinate with AgI and thus all the coordination sites of the ligand are employed. The results reveal the preference of AgI ion for the carbene carbon donor rather than the bpy units. The synthesis, structures, and interconversion of the complexes and the counteranion effects on the structures are reported, and the luminescent properties of the ligand LX and the silver complexes have also been studied. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/om201226s |
| Funding Organization | the National Natural Science Foundation of China (No. 20872149) |
| Indexed By | SCI |
| If | 4.145 |
| Language | 英语 |
| Funding Project | 金属有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3848 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Chinese Acad Sci, Graz Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Cui FJ,Yang PJ,Huang XJ,et al. Homometallic Silver(I) Complexes of a Heterotopic NHC-Bridged Bis-Bipyridine Ligand[J]. Organometallics,2012,31(9):3512-3518. |
| APA | Cui FJ,Yang PJ,Huang XJ,Yang XJ,Wu B,&吴彪.(2012).Homometallic Silver(I) Complexes of a Heterotopic NHC-Bridged Bis-Bipyridine Ligand.Organometallics,31(9),3512-3518. |
| MLA | Cui FJ,et al."Homometallic Silver(I) Complexes of a Heterotopic NHC-Bridged Bis-Bipyridine Ligand".Organometallics 31.9(2012):3512-3518. |
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| B4.Organometallics 2（411KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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