| Ordered mesoporous alumina supported nickel based catalysts for carbon dioxide reforming of methane | |
| Department | OSSO国家重点实验室 |
Xu LL(徐磊磊)1,2 ; Zhao HH(赵华华)1,2; Song HL(宋焕玲)1; Chou LJ(丑凌军)1; Chou LJ(丑凌军)
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| 2012 | |
| Source Publication | International Journal of Hydrogen Energy
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| ISSN | 0360-3199 |
| Volume | 37Issue:9Pages:7497-7511 |
| Abstract | Ordered mesoporous alumina facilely synthesized via improved evaporation-induced self-assembly (EISA) strategy was provided with large specific surface area, big pore volume, uniform pore size and excellent thermal stability. The obtained mesoporous material was used as the carrier of the Ni based catalysts for carbon dioxide reforming of methane. These mesoporous catalysts performed high catalytic activity and long stability. Typically, the catalytic conversions of the CH4 and CO2 were greatly close to the equilibrium conversion and no deactivation was observed during the 100 h long lifetime test. The advantageous structural properties of ordered mesoporous alumina contributed to high dispersion of the Ni particles among the mesoporous framework, which further accounted for the good catalytic activity due to more “accessible” Ni active sites for the reactants. The “confinement effect” of the mesopores could effectively prevent the thermal sintering of the Ni nanoparticles to some extent, committed to its long-term catalytic stability. Besides, the mesoporous catalysts possessed enhanced ability to withstand coke, although not any modifiers had been added. Properties of the coke over the mesoporous catalyst were also carefully investigated. Therefore, the ordered mesoporous alumina was a promising catalyst support for the carbon dioxide reforming with methane. |
| Keyword | Ordered Mesoporous Alumina Confinement Effect Carbon Dioxide Reforming Methane |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.ijhydene.2012.01.105 |
| Funding Organization | the National Basic Research Program of PR China (No. 2011CB201404);the National Natural Science Foundation of China (No. 21133011) |
| Indexed By | SCI |
| If | 3.548 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3842 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Xu LL,Zhao HH,Song HL,et al. Ordered mesoporous alumina supported nickel based catalysts for carbon dioxide reforming of methane[J]. International Journal of Hydrogen Energy,2012,37(9):7497-7511. |
| APA | Xu LL,Zhao HH,Song HL,Chou LJ,&丑凌军.(2012).Ordered mesoporous alumina supported nickel based catalysts for carbon dioxide reforming of methane.International Journal of Hydrogen Energy,37(9),7497-7511. |
| MLA | Xu LL,et al."Ordered mesoporous alumina supported nickel based catalysts for carbon dioxide reforming of methane".International Journal of Hydrogen Energy 37.9(2012):7497-7511. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 63.international jou（2492KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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