| Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids | |
| Department | 绿色化学与催化研发中心 |
Zhou HC(周瀚成); Shi F(石峰) ; Tian X(田雄); Zhang QH(张庆华); Deng YQ(邓友全)
| |
| 2007 | |
| Source Publication | Journal of Molecular Catalysis A: Chemical
 |
| ISSN | 1381-1169 |
| Volume | 271Pages:89-92 |
| Abstract | Selective synthesis of carbamates from amines and dimethyl carbonate were studied in the presence of various ionic liquids as catalysts. The –SO3H-functionalized ionic liquid was found to be the most active catalyst among the applied ionic liquids, and nearly 100% conversion and 95% selectivity were achieved when using 1,6-hexanediamine as reactant. The acid functional ionic liquid catalyst system is also readily separable and reusable after reaction. |
| Keyword | Green Chemistry Ionic Liquid Carbamates Amine Non-phosgene |
| Subject Area | 物理化学 |
| Funding Organization | National Natural Science Foundation of China (Nos. 20225309;20533080) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3652 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Zhou HC,Shi F,Tian X,et al. Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2007,271:89-92. |
| APA | 周瀚成,石峰,田雄,张庆华,&邓友全.(2007).Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids.Journal of Molecular Catalysis A: Chemical,271,89-92. |
| MLA | 周瀚成,et al."Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids".Journal of Molecular Catalysis A: Chemical 271(2007):89-92. |
| Files in This Item: | ||||||
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| 周瀚成JMC.pdf（203KB） | 开放获取 | License | View Application Full Text | |||
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