| Manganese Chloride as an Efficient Catalyst for Selective Transformations of Indoles in the Presence of a Keto Carbonyl Group | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Li MH(李明浩); Yang J(杨杰) ; Gu YL(顾彦龙)
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| 2011 | |
| Source Publication | Adv. Synth. Catal.
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| ISSN | 1615-4150 |
| Volume | 353Pages:1551-1564 |
| Abstract | Catalysis by manganese chloride tetrahydrate was found to be effective for the selective transformation of indoles, with which the desired acid-catalyzed reaction could be promoted and, at the same time, a side reaction that also needs assistance of acid, the electrophilic reaction of indole with the co-existing keto carbonyl group, does not occur. Some acid-catalyzed reactions, such as the ring-opening reaction of 2-alkoxy-3,4-dihydropyran with indole, and transesterification of b-keto ester with an alcohol that contains a C-3 unsubstituted indole fragment, could be performed smoothly by using manganese chloride as catalyst. A new multicomponent reaction of indole, 3,4-dihydropyran and b-keto ester was also developed with catalysis by manganese chloride. |
| Keyword | Acid Catalysis Indoles Manganese Chloride Selective Transformations Tandem Reactions |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Fundation of China for the financial support (20903042); Specialized Research Fund for the Doctoral Program of Higher Education (20090142120081);The Program for new Century Excellent Talents in the University of China (NCET-10-0383);Chutian Scholar Program of the Hubei provincial government |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/354 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Gu YL(顾彦龙) |
| Recommended Citation GB/T 7714 | Li MH,Yang J,Gu YL. Manganese Chloride as an Efficient Catalyst for Selective Transformations of Indoles in the Presence of a Keto Carbonyl Group[J]. Adv. Synth. Catal.,2011,353:1551-1564. |
| APA | 李明浩,杨杰,&顾彦龙.(2011).Manganese Chloride as an Efficient Catalyst for Selective Transformations of Indoles in the Presence of a Keto Carbonyl Group.Adv. Synth. Catal.,353,1551-1564. |
| MLA | 李明浩,et al."Manganese Chloride as an Efficient Catalyst for Selective Transformations of Indoles in the Presence of a Keto Carbonyl Group".Adv. Synth. Catal. 353(2011):1551-1564. |
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| 22-Adv. Synth. Catal（302KB） | 开放获取 | License | View Application Full Text | |||
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