| 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Shen ZL(沈振陆); Dai JL(戴佳亮); Xiong J(熊杰); He XJ(何喜军); Mo WM(莫卫民); Hu BX(胡宝祥); Sun N(孙楠); Hu XQ(胡信全) | |
| 2011 | |
| Source Publication | Adv. Synth. Catal.
 |
| ISSN | 1615-4150 |
| Volume | 353Pages:3031-3038 |
| Abstract | A new catalytic oxidation system using catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and tert-butyl nitrite with molecular oxygen serving as the environmentally benign, terminal oxidant has been developed. This aerobic catalytic system was established for the selective oxidation of non-sterically hindered benzylic alcohols and electron- rich benzyl methyl ethers, and successfully extended to an application in the oxidative deprotection of PMB ethers to the alcohols in high selectivity. |
| Keyword | Alcohols Deprotection Oxidation 2 Oxygen 3-dichloro-5 6-dicyano-1 4-benzoquinone (Ddq) |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Foundation of China (NSFC 20772111;20876149;21146001);the Zhejiang Provincial Natural Science Foundation of China (Y4090517) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/353 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Mo WM(莫卫民); Hu XQ(胡信全) |
| Recommended Citation GB/T 7714 | Shen ZL,Dai JL,Xiong J,et al. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System[J]. Adv. Synth. Catal.,2011,353:3031-3038. |
| APA | 沈振陆.,戴佳亮.,熊杰.,何喜军.,莫卫民.,...&胡信全.(2011).2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System.Adv. Synth. Catal.,353,3031-3038. |
| MLA | 沈振陆,et al."2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System".Adv. Synth. Catal. 353(2011):3031-3038. |
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| File Name/Size | DocType | Version | Access | License | ||
| 23-Adv. Synth. Catal（242KB） | 开放获取 | License | View Application Full Text | |||
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