| Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Qian B(钱波); Jie P(解攀) ; Xie YJ(谢银君); Huang HM(黄汉民)
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| 2011 | |
| Source Publication | Org. Lett.
 |
| ISSN | 1523-7060 |
| Volume | 13Issue:10Pages:2580-2583 |
| Abstract | A novel iron-catalyzed alkenylation of 2-substituted azaarenes through sp3 C H bond activation has been developed. A favorable E2-elimination is proposed as a key step to cleavage of C H and C N bonds for the construction of a CdC bond in high stereoselectivity. This transformation represents an efficient way to synthesize 2-alkenylated azaarenes from simple starting materials. |
| Subject Area | 有机功能材料 |
| Funding Organization | the National Natural Science Foundation of China (2080- 2085) and Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 有机功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/347 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Recommended Citation GB/T 7714 | Qian B,Jie P,Xie YJ,et al. Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation[J]. Org. Lett.,2011,13(10):2580-2583. |
| APA | 钱波,解攀,谢银君,&黄汉民.(2011).Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation.Org. Lett.,13(10),2580-2583. |
| MLA | 钱波,et al."Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation".Org. Lett. 13.10(2011):2580-2583. |
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| 25-Org. Lett., 2011,（747KB） | 开放获取 | License | View Application Full Text | |||
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