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Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate
Department固体润滑国家重点实验室
Wan Y(万勇)1; Wang YH(王银虎)1; Zhang Q(张全)1; Wang ZQ(王忠乾)1; Xu Z(许震)1; Liu ZS(刘长松)1; Zhang JY(张俊彦)2; Wan Y(万勇)
2012
Source PublicationApplied Surface Science
ISSN0169-4332
Volume259Pages:147-152
AbstractA simple two-step process was developed to render the copper surface with lower friction and long durability. The copper substrate was immersed in a 0.01 M NaOH solution to fabricate a textured Cu2O film. A self-assembled monolayer of alkylphosphonic acid was then deposited on the Cu2O film to acquire high hydrophobicity. Scanning electron microscopy, Fourier transform infrared microscopy and water contact angle measurements were used to analyze the morphological features, the chemical composition and hydrophobicity of freshly prepared samples, respectively. Moreover, the friction-reducing behavior of the organic-inorganic composite film sliding against steel was evaluated in a ball-on-plate configuration. It was found that the alkylphosphonic acid films on the textured Cu2O film led to decreased friction with significantly extended life. For a constant load, the increase in chain length of alkylphosphonic acid yields the films that are dramatically more stable against tribological deformation and provide low coefficients of friction over much longer periods of time.
KeywordThin Film Friction Self-assembled Monolayer Chemical Etching Copper
Subject Area材料科学与物理化学
DOI10.1016/j.apsusc.2012.07.008
Funding Organizationthe Natural Science Foundation of Shandong Province (Y2008F05);the Applied and Basic Research Foundation of Qingdao City (09-1-3-35-jch)
Indexed BySCI
If2.112
Language英语
Funding Project纳米润滑研究组
compositor第二作者单位
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/3296
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWan Y(万勇)
Affiliation1.Qingdao Technol Univ, Sch Mech Engn, Qingdao 266033, Peoples R China
2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Wan Y,Wang YH,Zhang Q,et al. Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate[J]. Applied Surface Science,2012,259:147-152.
APA Wan Y.,Wang YH.,Zhang Q.,Wang ZQ.,Xu Z.,...&万勇.(2012).Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate.Applied Surface Science,259,147-152.
MLA Wan Y,et al."Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate".Applied Surface Science 259(2012):147-152.
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