| Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Li MR(李敏睿); Wu B(吴彪); Cui FJ(崔凤娟); Hao YJ(郝勇静); Huang XJ(黄晓卷) ; Yang XJ(杨晓娟)
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| 2011 | |
| Source Publication | Z. Anorg. Allg. Chem.
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| ISSN | 0044-2313 |
| Volume | 637Pages:2306-2311 |
| Abstract | Two anion complexes of a tripodal tris(ferrocenylurea) receptor (L), (LH)·CF3SO3 (1) and (LH)·HSO4 (2), were obtained from L and triflic acid or sulfuric acid, respectively. Crystal structural analyses show that the receptor in the two 1:1 (host/guest) complexes isprotonated (on the bridgehead tertiary amine), and the CF3SO3 – or HSO4 – anion is located outside the tripodal cavity and anchored by the urea and CH groups of the receptor by hydrogen bonds. 1H NMR spectroscopic studies confirmed the binding mode in solution. |
| Keyword | Tripodal Tris-urea Receptors Ferrocene Anion Binding Protonation Nmr Spectroscopy |
| Subject Area | 金属有机 |
| Funding Organization | the National Natural Science Foundation of China (20872149) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/322 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Li MR,Wu B,Cui FJ,et al. Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor[J]. Z. Anorg. Allg. Chem.,2011,637:2306-2311. |
| APA | 李敏睿,吴彪,崔凤娟,郝勇静,黄晓卷,&杨晓娟.(2011).Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor.Z. Anorg. Allg. Chem.,637,2306-2311. |
| MLA | 李敏睿,et al."Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor".Z. Anorg. Allg. Chem. 637(2011):2306-2311. |
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