| Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Gao J(高静); Liu YY(刘艳艳); Zhao YX(赵艳霞); Yang XJ(杨晓娟) ; Sui YX(隋云霞)
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| 2011 | |
| Source Publication | Organometallics
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| ISSN | 0276-7333 |
| Volume | 30Issue:22Pages:6071-6077 |
| Abstract | The reduction of neutral α-diimine ligands bearing different substituents on the N-aryl rings by different amounts of potassium metal and subsequent reaction with anhydrous MgCl2 in THF afforded a series of magnesium compounds, [(LiPr)2−Mg- (THF)2]·THF (2), [(LMes)2−Mg(THF)3] (3), [(LiPr)− 2Mg]·THF (4), [(LMes)− 2Mg] (5), and [(LMes)2− 2Mg(η 6:η 6-K(THF)2)][K(THF)6]·(THF)2 (6) (LiPr = [(2,6-iPr2C6H3)NC- (Me)]2), LMes = [(2,4,6-Me3C6H2)NC(Me)]2). Complexes 2−6 have been characterized by single-crystal X-ray diffraction, elemental analysis, NMR spectroscopy, and EPR studies (for 4 and 5). The noninnocent α-diimine ligands exist as the dianionic form in compounds 2, 3, and 6 and as a monoanion in 4 and 5. Effects of the ligand substituents and the amount of the reducing agent on the structure of the product have been discussed. |
| Subject Area | 金属有机 |
| Funding Organization | the National Natural Science Foundation of China (20771103 and 20972169) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/321 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Yang XJ(杨晓娟) |
| Recommended Citation GB/T 7714 | Gao J,Liu YY,Zhao YX,et al. Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands[J]. Organometallics,2011,30(22):6071-6077. |
| APA | 高静,刘艳艳,赵艳霞,杨晓娟,&隋云霞.(2011).Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands.Organometallics,30(22),6071-6077. |
| MLA | 高静,et al."Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands".Organometallics 30.22(2011):6071-6077. |
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