| Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides | |
| Department | 羰基合成与选择氧化国家重点实验室（OSSO） |
Han B(韩波)1,2; Ren CP(任春平)1; Wu LP(吴立朋)1
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| The second department | 吴立朋人才团队 |
| 2023-03-02 | |
| Source Publication | Organometallics
 |
| Volume | 42Issue:12Pages:1248-1253 |
| Abstract | Hydrodehalogenation is a straightforward approach to detoxifying harmful organohalides, in which the halogen atom is formally substituted with a hydrogen atom. Herein, a catalytic system using Cp2TiCl2 as the catalyst and ammonia–borane as the reductant is described. A series of benzyl halides and inactivated alkyl halides (including alkyl chlorides) readily reacted to give the corresponding hydrodehalogenated products in yields of up to 97% (43 examples). |
| Keyword | 钛 催化 卤代烷烃 加氢脱卤 |
| MOST Discipline Catalogue | 理学::化学 |
| DOI | 10.1021/acs.organomet.2c00632 |
| URL | 查看原文 |
| Indexed By | SCI |
| If | 2.8 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/30577 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Han B(韩波) |
| Affiliation | 1.中国科学院兰州化学物理研究所 2.中国科学院大学 |
| Corresponding Author Affilication | Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Han B,Ren CP,Wu LP. Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides[J]. Organometallics,2023,42(12):1248-1253. |
| APA | Han B,Ren CP,&Wu LP.(2023).Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides.Organometallics,42(12),1248-1253. |
| MLA | Han B,et al."Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides".Organometallics 42.12(2023):1248-1253. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| han-et-al-2023-titan（1573KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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