| Direct 2-Pyridyl-Alkylation of Benzyne with N-Alkylpyridinium Salts | |
| Department | 羰基合成与选择氧化国家重点实验室（OSSO） |
Su YJ(苏毅进)
| |
| The second department | 苏毅进人才团队 |
| 2023-03 | |
| Source Publication | Synthesis
 |
| Issue | 14Pages:2159-2165 |
| Abstract | A 2-pyridyl-alkylation of benzyne using N-alkylpyridinium salts has been developed under either photochemical or thermal conditions. This metal-free dicarbofunctionalization of benzyne undergoes a de Mayo-type process including cascade dearomative [3+2] cycloaddition and rearomative ring-opening reaction. An electron-deficient N-cyclic alkyl group was necessary. A formal ortho-C–H arylation of pyridine has been achieved. |
| DOI | 10.1055/a-2050-6508 |
| If | 2.6 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/30558 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Su YJ(苏毅进) |
| Recommended Citation GB/T 7714 | Su YJ. Direct 2-Pyridyl-Alkylation of Benzyne with N-Alkylpyridinium Salts[J]. Synthesis,2023(14):2159-2165. |
| APA | Su YJ.(2023).Direct 2-Pyridyl-Alkylation of Benzyne with N-Alkylpyridinium Salts.Synthesis(14),2159-2165. |
| MLA | Su YJ."Direct 2-Pyridyl-Alkylation of Benzyne with N-Alkylpyridinium Salts".Synthesis .14(2023):2159-2165. |
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