Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt

doi:10.1002/anie.202111978

LICP OpenIR

	Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt
Department	羰基合成与选择氧化国家重点实验室（OSSO）
	Li SD(李思达)1; Hu CY(胡晨阳)2; Cui X(崔鑫)1; Zhang J(张炯)1; Liu L(刘柳)2; Wu LP(吴立朋)1
The second department	吴立朋人才团队
	2021-11
Source Publication	Angew. Chem., Int. Ed.
Issue	未出 Pages:未出
Abstract	A novel and general method for the hydroboration of alkenes, including aryl alkenes, 1,1-disubstituted alkenes, aliphatic alkenes, and bio-derived alkenes, using BX₃ as the boration reagent in the presence of ⁱPr₂NEt is reported. The reaction was also applied to the synthesis of linear and branched 1,n-diborylalkanes. The reaction is thought to proceed by a frustrated Lewis pair type single-electron-transfer mechanism.
MOST Discipline Catalogue	理学::化学
DOI	10.1002/anie.202111978
URL	查看原文
Indexed By	SCI
If	15.336
Language	英语
compositor	第一作者单位
Citation statistics	Cited Times:21[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/27553
Collection	中国科学院兰州化学物理研究所
Corresponding Author	Liu L(刘柳); Wu LP(吴立朋)
Affiliation	1.中国科学院兰州化学物理研究所 2.南方科技大学
Corresponding Author Affilication	Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences
Recommended Citation GB/T 7714	Li SD,Hu CY,Cui X,et al. Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt[J]. Angew. Chem., Int. Ed.,2021(未出):未出.
APA	Li SD,Hu CY,Cui X,Zhang J,Liu L,&Wu LP.(2021).Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt.Angew. Chem., Int. Ed.(未出),未出.
MLA	Li SD,et al."Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt".Angew. Chem., Int. Ed. .未出(2021):未出.

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