Catalytic Boration of Alkyl Halides with Borane without Hydrodehalogenation Enabled by Titanium Catalyst

doi:10.1002/anie.202100569

LICP OpenIR

	Catalytic Boration of Alkyl Halides with Borane without Hydrodehalogenation Enabled by Titanium Catalyst
Department	羰基合成与选择氧化国家重点实验室（OSSO）
	Wang XJ(王先津)1; Cui PL(崔鹏雷)2; Xia CG(夏春谷)1 ; Wu LP(吴立朋)1
The second department	吴立朋人才团队
	2021-05
Source Publication	Angew. Chem., Int. Ed.
Volume	60 Issue:22 Pages:12298-12303
Abstract	A general titanium-catalyzed boration of alkyl (pseudo)halides with boranes is reported. The system can successfully suppress the undesired hydrodehalogenation process that prevails using other transition-metal catalysts. The current strategy worked for various alkyl electrophiles, including unactivated alkyl chlorides, with tolerance of reducing functional groups such as ester, alkene, and carbamate. Mechanistic studies reveal a possible radical reaction pathway.
Keyword	boration，alkyl halide，titanium
MOST Discipline Catalogue	理学::化学
DOI	10.1002/anie.202100569
URL	查看原文
Indexed By	SCI
If	15.336
Language	英语
compositor	第一作者单位
Citation statistics	Cited Times:11[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/27536
Collection	中国科学院兰州化学物理研究所
Corresponding Author	Xia CG(夏春谷); Wu LP(吴立朋)
Affiliation	1.中国科学院兰州化学物理研究 2.河北农业大学
Recommended Citation GB/T 7714	Wang XJ,Cui PL,Xia CG,et al. Catalytic Boration of Alkyl Halides with Borane without Hydrodehalogenation Enabled by Titanium Catalyst[J]. Angew. Chem., Int. Ed.,2021,60(22):12298-12303.
APA	Wang XJ,Cui PL,Xia CG,&Wu LP.(2021).Catalytic Boration of Alkyl Halides with Borane without Hydrodehalogenation Enabled by Titanium Catalyst.Angew. Chem., Int. Ed.,60(22),12298-12303.
MLA	Wang XJ,et al."Catalytic Boration of Alkyl Halides with Borane without Hydrodehalogenation Enabled by Titanium Catalyst".Angew. Chem., Int. Ed. 60.22(2021):12298-12303.

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