| Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Tao FR(陶芙蓉); Song HL(宋焕玲) ; Chou LJ(丑凌军)
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| 2011 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 1Pages:672-676 |
| Abstract | A simple and effective process for the dehydration of fructose into 5-hydroxymethylfurfural (HMF) using ionic liquid 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulfate (IL-1) as the catalyst was developed. High fructose conversion of 100% with HMF yield of 94.6% was obtained at 120 uC for 180 min reaction time in water-4-methyl-2-pentanone (MIBK) biphase system. Generally, the increase of water content had a negative effect on the reaction, the HMF selectivity decreased as the excessive elevation of temperature and prolonging of time, which suggested the decomposition of HMF. The ionic liquid IL-1 could be recycled and exhibited constant activity for six successful runs. This paper provided a new strategy for HMF production from fructose. |
| Subject Area | 多相催化 |
| Funding Organization | the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 多相催化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/274 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Recommended Citation GB/T 7714 | Tao FR,Song HL,Chou LJ. Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids[J]. RSC Advances,2011,1:672-676. |
| APA | 陶芙蓉,宋焕玲,&丑凌军.(2011).Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids.RSC Advances,1,672-676. |
| MLA | 陶芙蓉,et al."Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids".RSC Advances 1(2011):672-676. |
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| File Name/Size | DocType | Version | Access | License | ||
| 129-RSC Adv., 2011,（461KB） | 开放获取 | License | View Application Full Text | |||
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