Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination | |
Department | 羰基合成与选择氧化国家重点实验室(OSSO) |
许诺; 徐佳能; 朱庆; 刘超 | |
The second department | 刘超课题组 |
2020-12 | |
Source Publication | Advanced Synthesis & Catalysis |
Issue | 363Pages:2403-2407 |
Abstract | A method for the synthesis of allylboronates via Zweifel-type deprotonative olefination was demonstrated. Tetrasubstituted vinylboronates were used as the substrates. NCS (N-chlorosuccinimide) was used as a bifunctional additive, electrophile and base. This method exhibited a different elimination strategy in Zweifel type transformation to afford allylboronates. The homo-alcohols and alkenes were stereoselective synthesized from the obtained allylboronates, demonstrating the synthetic value of this methodology. |
Keyword | Boron Allylic Compounds Vinylboronates Zweifel Olefination |
If | 4.900 |
compositor | 第一作者单位 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/27485 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | 许诺 |
Recommended Citation GB/T 7714 | 许诺,徐佳能,朱庆,等. Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination[J]. Advanced Synthesis & Catalysis,2020(363):2403-2407. |
APA | 许诺,徐佳能,朱庆,&刘超.(2020).Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination.Advanced Synthesis & Catalysis(363),2403-2407. |
MLA | 许诺,et al."Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination".Advanced Synthesis & Catalysis .363(2020):2403-2407. |
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adsc.202001351.pdf(5578KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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