LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination
Department羰基合成与选择氧化国家重点实验室(OSSO)
许诺; 徐佳能; 朱庆; 刘超
The second department刘超课题组
2020-12
Source PublicationAdvanced Synthesis & Catalysis
Issue363Pages:2403-2407
Abstract

A method for the synthesis of allylboronates via Zweifel-type deprotonative olefination was demonstrated. Tetrasubstituted vinylboronates were used as the substrates. NCS (N-chlorosuccinimide) was used as a bifunctional additive, electrophile and base. This method exhibited a different elimination strategy in Zweifel type transformation to afford allylboronates. The homo-alcohols and alkenes were stereoselective synthesized from the obtained allylboronates, demonstrating the synthetic value of this methodology.

KeywordBoron Allylic Compounds Vinylboronates Zweifel Olefination
If4.900
compositor第一作者单位
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/27485
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding Author许诺
Recommended Citation
GB/T 7714
许诺,徐佳能,朱庆,等. Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination[J]. Advanced Synthesis & Catalysis,2020(363):2403-2407.
APA 许诺,徐佳能,朱庆,&刘超.(2020).Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination.Advanced Synthesis & Catalysis(363),2403-2407.
MLA 许诺,et al."Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination".Advanced Synthesis & Catalysis .363(2020):2403-2407.
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