| Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts | |
| Suo, Hongyi1,2,3; Solan, Gregory A.1,2,4; Ma, Yanping1,2; Sun, Wen-Hua1,2,3,5 | |
| 2018-10-01 | |
| Corresponding Author | Solan, Gregory A.(gas8@leicester.ac.uk) ; Sun, Wen-Hua(whsun@iccas.ac.cn) |
| Source Publication | COORDINATION CHEMISTRY REVIEWS
 |
| ISSN | 0010-8545 |
| Volume | 372Pages:101-116 |
| Abstract | Recent progress concerning the application of compartmentalized bimetallic complexes as homogeneous catalysts in ethylene polymerization is reviewed with particular regard to metal-metal combinations based on either early- (Ti, Zr, Hf and V) or late-transition metals (Fe, Co and Ni). The effect of positioning two polymerization-active metal centers in close proximity on catalytic activity, molecular weight, molecular weight distribution and levels of branching are thoroughly documented. Compartmental ligands comprising binding domains consisting of phenoxyimines, ansa-bridged cyclopentadienyl-amides, alpha-diimines and iminopyridines are described as is their capacity to serve as compatible binucleating supports for homobimetallic and also for the less investigated heterobimetallic counterparts. By comparison with their mononuclear analogues, any synergic properties exhibited by these binuclear catalysts represents an underlying theme to be developed where possible throughout this review. (C) 2018 Elsevier B.V. All rights reserved. |
| Keyword | Bimetallic complex Early transition metal Late transition metal Catalyst Compartmental ligand Ethylene polymerization Polyethylene microstructure |
| DOI | 10.1016/j.ccr.2018.06.006 |
| Funding Organization | National Natural Science Foundation of China ; UCAS Joint PhD Training Program ; Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[U1362204] ; National Natural Science Foundation of China[21374123] ; UCAS Joint PhD Training Program[UCAS[2017]17] ; Chinese Academy of Sciences |
| WOS Research Area | Chemistry |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/27222 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Solan, Gregory A.; Sun, Wen-Hua |
| Affiliation | 1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100049, Peoples R China 4.Univ Leicester, Dept Chem, Univ Rd, Leicester LE1 7RH, Leics, England 5.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Suo, Hongyi,Solan, Gregory A.,Ma, Yanping,et al. Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts[J]. COORDINATION CHEMISTRY REVIEWS,2018,372:101-116. |
| APA | Suo, Hongyi,Solan, Gregory A.,Ma, Yanping,&Sun, Wen-Hua.(2018).Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts.COORDINATION CHEMISTRY REVIEWS,372,101-116. |
| MLA | Suo, Hongyi,et al."Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts".COORDINATION CHEMISTRY REVIEWS 372(2018):101-116. |
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