KMS Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences
Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes | |
Department | 羰基合成与选择氧化国家重点实验室(OSSO) |
王先津1,3; 崔鑫1; 李思达1; 王玥1; 夏春谷1; 焦海军2; 吴立朋1 | |
The second department | 吴立朋人才团队 |
2020-07 | |
Source Publication | Angew. Chem., Int. Ed. |
Issue | 59Pages:13608 |
Abstract | A general and atom‐economical synthesis of 1,1‐diborylalkanes from alkenes and a borane without the need for an additional H2 acceptor is reported for the first time. The key to our success is the use of an earth‐abundant zirconium‐based catalyst, which allows a balance of self‐contradictory reactivities (dehydrogenative boration and hydroboration) to be achieved. Our method avoids using an excess amount of another alkene as an H2 acceptor, which was required in other reported systems. Furthermore, substrates such as simple long‐chain aliphatic alkenes that did not react before also underwent 1,1‐diboration in our system. Significantly, the unprecedented 1,1‐diboration of internal alkenes enabled the preparation of 1,1‐diborylalkanes. |
URL | 查看原文 |
If | 12.959 |
compositor | 第一作者单位 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/26972 |
Collection | 中国科学院兰州化学物理研究所 |
Corresponding Author | 王先津; 焦海军; 吴立朋 |
Affiliation | 1.兰州化物所 2.德国莱布尼茨催化研究所 3.中国科学院大学 |
Recommended Citation GB/T 7714 | 王先津,崔鑫,李思达,等. Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes[J]. Angew. Chem., Int. Ed.,2020(59):13608. |
APA | 王先津.,崔鑫.,李思达.,王玥.,夏春谷.,...&吴立朋.(2020).Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes.Angew. Chem., Int. Ed.(59),13608. |
MLA | 王先津,et al."Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes".Angew. Chem., Int. Ed. .59(2020):13608. |
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anie.202002642.pdf(1221KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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