| Catalytic hydrolysis of cellulose into furans in MnCl2-ionic liquid system | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Tao FR(陶芙蓉); Song HL(宋焕玲) ; Yang J(杨建); Chou LJ(丑凌军)
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| 2011 | |
| Source Publication | Carbohydr. Polym.
 |
| ISSN | 0144-8617 |
| Volume | 85Issue:2Pages:363-368 |
| Abstract | Production of 5-hydroxymethylfurfural (HMF) and furfural from microcrystalline cellulose (MCC) was studied in 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulfate (IL-1) with catalytic amount of MnCl2 under atmospheric pressure within 300 min at 150 ◦C, in which 88.62% of conversion was obtained. With the presence of a catalytic amount of MnCl2, HMF and furfural yields were up to 37% and 18%, respectively, and generated small amount of levulinic acid (LA) and the total reducing sugars (TRS). Dimer of furans compounds as the important by-products were analyzed through HPLC–MS; some small molecular substances, methane, ethane, CO, CO2 and H2, as gas products were detected using mass spectrometry analysis. Comparing with the previous reports, our catalytic system is simple, and it provides an effective route for the conversion of microcrystalline cellulose into biofuels and important platform chemicals. |
| Keyword | Microcrystalline Cellulose Hydrolysis Ionic Liquids Hmf Furfural Mncl2 |
| Subject Area | 多相催化 |
| Funding Organization | the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 多相催化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/267 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Recommended Citation GB/T 7714 | Tao FR,Song HL,Yang J,et al. Catalytic hydrolysis of cellulose into furans in MnCl2-ionic liquid system[J]. Carbohydr. Polym.,2011,85(2):363-368. |
| APA | 陶芙蓉,宋焕玲,杨建,&丑凌军.(2011).Catalytic hydrolysis of cellulose into furans in MnCl2-ionic liquid system.Carbohydr. Polym.,85(2),363-368. |
| MLA | 陶芙蓉,et al."Catalytic hydrolysis of cellulose into furans in MnCl2-ionic liquid system".Carbohydr. Polym. 85.2(2011):363-368. |
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