Synthesis and physicochemical characterization of polyoxymethylene dimethyl ethers | |
Department | OSSO国家重点实验室 |
Kang MR(康美荣); Song HY(宋河远); Jin FX(金福祥)); Chen J(陈静) | |
The second department | 分子催化与技术 |
2017-07 | |
Source Publication | Journal of Fuel Chemistry and Technology |
Volume | 45Issue:7Pages:837-845 |
Abstract | Polyoxymethylene dimethyl ethers (H3CO(CH2O)nCH3, PODEn, DMMn, n≥2) with unique physical and chemical properties open a new route for energy conservation and emission reduction of diesel fuels and can also be used in various industrial fields. The present work firstly prepared a series of high purity single component compound of PODEn with increasing the number of repeating units (n) from 2 to 5. The structures of the samples were characterized by NMR, IR, Raman and DFT. The mass density and viscosity of PODEn were measured in the range of 298.15 to 323.15 K. The densities and viscosities gradually decreased with the increase of temperature. While the density and viscosity values gradually enlarged with the number of –CH2O– units from 2 to 5. The flash point and pour point of PODEn (n = 2 to 5) were also measured, they all increased with the chain length. The DSC of samples were texted, the absorbed latent heat and released latent heat increased with the degree of polymerization increasing. |
Keyword | polyoxymethylene dimethyl ethers synthesis structural characterization physicochemical property |
Indexed By | EI |
If | 1.278 |
Language | 英语 |
compositor | 第一作者单位 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/26425 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Chen J(陈静) |
Affiliation | 中科院兰州化学物理研究所 |
Recommended Citation GB/T 7714 | Kang MR,Song HY,Jin FX,et al. Synthesis and physicochemical characterization of polyoxymethylene dimethyl ethers[J]. Journal of Fuel Chemistry and Technology,2017,45(7):837-845. |
APA | Kang MR,Song HY,Jin FX,&Chen J.(2017).Synthesis and physicochemical characterization of polyoxymethylene dimethyl ethers.Journal of Fuel Chemistry and Technology,45(7),837-845. |
MLA | Kang MR,et al."Synthesis and physicochemical characterization of polyoxymethylene dimethyl ethers".Journal of Fuel Chemistry and Technology 45.7(2017):837-845. |
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