Optimization of Cu catalysts for nitrophenol reduction, click reaction and alkyne coupling | |
Department | ERC国家工程研究中心 |
Huang Y(黄昱)1; Zheng K(郑凯博)1; Liu X(刘湘)1; Meng X(孟旭)2; Didier Astruc3 | |
The second department | 催化新工艺 |
2019-12 | |
Source Publication | INORGANIC CHEMISTRY FRONTIERS |
Issue | 7Pages:939-945 |
Abstract | Earth-abundant nanocatalysts are actively searched to replace expensive noble metal catalysts for a number of essential processes. Here, Cu catalysts have been designed based on manganese oxide octahedral molecular sieve (OMS-2) supports to optimize the catalytic activity in nitrophenol reduction, CuAAC click reaction and terminal alkyne homocoupling. A correlation has been established between the different synthetic strategies and catalytic activities. CuOx/OMS-2 has also been found an efficient catalyst for the homocoupling of terminal alkynes, click reaction and the reduction of 4-nitrophenol, 2,4-dinitrophenol and 4-nitrobenzene diazo tetrafluoroborate with high activity, whereas Cu-OMS-2 only shows poor catalytic activity for reduction and click reaction, and no catalytic activity for homocoupling. |
DOI | 10.1039/c9qi01449g |
Indexed By | SCI |
If | 5.934 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/26262 |
Collection | 苏州研究院 |
Corresponding Author | Liu X(刘湘); Meng X(孟旭); Didier Astruc |
Affiliation | 1.三峡大学 2.中科院兰化所 3.法国波尔多大学 |
Recommended Citation GB/T 7714 | Huang Y,Zheng K,Liu X,et al. Optimization of Cu catalysts for nitrophenol reduction, click reaction and alkyne coupling[J]. INORGANIC CHEMISTRY FRONTIERS,2019(7):939-945. |
APA | Huang Y,Zheng K,Liu X,Meng X,&Didier Astruc.(2019).Optimization of Cu catalysts for nitrophenol reduction, click reaction and alkyne coupling.INORGANIC CHEMISTRY FRONTIERS(7),939-945. |
MLA | Huang Y,et al."Optimization of Cu catalysts for nitrophenol reduction, click reaction and alkyne coupling".INORGANIC CHEMISTRY FRONTIERS .7(2019):939-945. |
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2020-ICF.pdf(3830KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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